145483-70-1Relevant articles and documents
A facile synthesis of 1,4-dialkoxy-2,5-diiodobenzenes: reaction of dialkoxybenzenes with iodine monochloride in alcoholic solvents
Wariishi, Koji,Morishima, Sin-Ichi,Inagaki, Yoshio
, p. 98 - 100 (2003)
A facile synthesis of 1,4-dialkoxy-2,5-diiodobenzenes via diiodination of the corresponding dialkoxybenzenes with iodine monochloride has been developed. Employment of ah alcoholic solvent as a reaction medium is crucial for attaining a high yield; the reaction in a nonalcoholic solvent usually resulted in a poor yield. The diiodobenzene derivatives are useful intermediates in the synthesis of such advanced materiais as soluble phenylenevinylene polymers anal dialkoxy derivatives of 7,7,8,8-tetracyanoquinodimethane.
Triphenylamine and terpyridine-zinc(ii) complex based donor-acceptor soft hybrid as a visible light-driven hydrogen evolution photocatalyst
Ghorai, Manas K.,Kar, Kamal K.,Kumar, Manish,Maji, Tapas Kumar,Samanta, Debabrata,Singh, Sugandha,Verma, Parul
, p. 21968 - 21972 (2020/11/11)
A donor-acceptor coordination polymer (TPA-Zn) was synthesized by Zn(ii)-assisted self-assembly of an in situ generated triphenylamine (TPA) cored tristerpyridine ligand. The polymer absorbs a broad-spectrum of light and exhibits visible light-assisted hydrogen generation (27.1 mmol g-1 over 9 h) from water with 2.9% quantum efficiency at 400 nm. The microscopy images show a mesoscale fibrous morphology and the Brunauer-Emmett-Teller (BET) analysis reveals the porous nature of TPA-Zn (surface area: 234.5 m2 g; d = 6.98 nm), both of which are helpful for substrate diffusion during catalysis. This journal is
A helical chiral polymer-based chromo-fluorescence and CD response sensor for selective detection of trivalent cations
Wang, Lu,Li, Fei,Liu, Xunhua,Wei, Guo,Cheng, Yixiang,Zhu, Chengjian
, p. 4070 - 4075 (2013/09/23)
A novel chiral (S)-BINAM-based fluorescent polymer sensor was designed and synthesized by the polymerization of 4,4′-((2,5-dibutoxy-1,4-phenylene) bis(ethyne-2,1-diyl))-dibenzaldehyde (M-1) with (S)-2,2′-binaphthyldiamine (S-BINAM, M-2) via Schiff's base formation. The resulting helical chiral polymer sensor exhibited remarkable turn-on bright blue fluorescence color upon the addition of trivalent metal ions under a commercially available UV lamp; this change can be clearly observed by the naked eye for direct visual discrimination at low concentration. More importantly, the addition of trivalent metal cations can lead to a most pronounced change of CD spectra of the chiral polymer indicating this kind chiral sensor can also be used as a sole probe for selective recognition of trivalent metal cations based on CD spectra.
Homoleptic "star" Ru(II) polypyridyl complexes: Shielded chromophores to study charge-transfer at the sensitizer-TiO2 interface
Johansson, Patrik G.,Zhang, Yongyi,Meyer, Gerald J.,Galoppini, Elena
, p. 7947 - 7957 (2013/08/23)
Three homoleptic star-shaped ruthenium polypyridyl complexes, termed Star YZ1, Star YZ2, and Star YZ3, where the Ru(II) center is coordinated to three bipyridine ligands each carrying two oligo(phenylene ethynylene) (OPE) rigid linker units terminating wi