294674-96-7Relevant articles and documents
Evaluation of the β value of the phenylene ethynylene unit by probing the exchange interaction between two nitronyl nitroxides
Shinomiya, Masataka,Higashiguchi, Kenji,Matsuda, Kenji
, p. 9282 - 9290 (2013/10/08)
A series of nitronyl nitroxide radicals having different lengths of phenylene ethynylene molecular wire were synthesized to investigate the decay constant of p-phenylene ethynylene. By the measurement and simulation of the ESR spectra of the biradicals, i
Polymer-based fluorescence sensor incorporating triazole moieties for Hg2+ detection via click reaction
Huang, Xiaobo,Meng, Jie,Dong, Yu,Cheng, Yixiang,Zhu, Chengjian
experimental part, p. 3064 - 3067 (2011/11/12)
The polymer could be obtained by the polymerization of 1,4-dibutoxy-2,5-diethynylbenzene (M-1) with 1,4-diazidobenzene (M-2) via click reaction. The polymer show blue fluorescence. The responsive optical properties of the polymer on various transition metal ions were investigated by fluorescence spectra. Compared with other cations, such as Co2+, Ni2+, Ag+, Cd2+, Cu2+ and Zn2+, Hg2+ can exhibit the most pronounced fluorescence response of the polymer Hg2+ can exhibit the most pronounced fluorescence response of the polymer due to triazole moiety in the polymer main chain as the metal binding ligand. The results indicate this kind of conjugated polymer with triazole moiety synthesized by click reaction can be used as a selective fluorescence sensor for Hg2+ detection.