145489-91-4

Basic information

• Product Name: 4-acetyl-3-hydroxy-6-nitro-2-phenyliodonio-phenolate
• Synonyms: 4-acetyl-3-hydroxy-6-nitro-2-phenyliodonio-phenolate
• CAS NO: 145489-91-4
• Molecular Weight: 399.142
• Mol File: 145489-91-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-acetyl-3-hydroxy-6-nitro-2-phenyliodonio-phenolate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-acetyl-3-hydroxy-6-nitro-2-phenyliodonio-phenolate(145489-91-4)
• EPA Substance Registry System: 4-acetyl-3-hydroxy-6-nitro-2-phenyliodonio-phenolate(145489-91-4)

Safety Data

• Hazardous Substances Data: 145489-91-4(Hazardous Substances Data)

Upstream product

• 3328-77-6 1-(2,4-dihydroxy-5-nitrophenyl)ethanone 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 3240-34-4 [bis(acetoxy)iodo]benzene 

Downstream Products

• 145489-93-6 2-hydroxy-3-iodo-4-phenoxy-5-nitro-acetophenone 

Relevant articles and documents

Hypervalent iodine oxidation of α-substituted 2,4-dihydroxyacetophenones: Synthesis of novel o-iodophenoxy ethers via rearrangement of iodonium ylides

α-Substituted 2,4-dihydroxyacetophenones (1a-1i) have been oxidized with phenyliodonium diacetate (PIDA) under three conditions (i) PIDA-KOH-MeOH (basic) at 0°C, (ii) PIDA-MeOH (neutral) at reflux temperature, and (iii) PIDA-AcOH (acidic) at reflux temper

Hypervalent iodine oxidation of some 2,4-dihydroxyacetophenones with iodobenzene diacetate potassium hydroxide in methanol : A novel route to 2-hydroxy-3-iodo-4-phenoxyacetophenones

Hypervalent iodine oxidation of some 2,4-dihydroxyacetophenones (2a-d) with C6H5I (OAc)2 - KOH/MeOH providing a novel route to 2-hydroxy-3-iodo-4-phenoxyacetophenones (3a-d) via the rearrangement of iodonium ylides is repo