145489-93-6

Basic information

• Product Name: 2-hydroxy-3-iodo-4-phenoxy-5-nitro-acetophenone
• Synonyms: 2-hydroxy-3-iodo-4-phenoxy-5-nitro-acetophenone
• CAS NO: 145489-93-6
• Molecular Weight: 399.142
• Mol File: 145489-93-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-hydroxy-3-iodo-4-phenoxy-5-nitro-acetophenone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-hydroxy-3-iodo-4-phenoxy-5-nitro-acetophenone(145489-93-6)
• EPA Substance Registry System: 2-hydroxy-3-iodo-4-phenoxy-5-nitro-acetophenone(145489-93-6)

Safety Data

• Hazardous Substances Data: 145489-93-6(Hazardous Substances Data)

Upstream product

• 3328-77-6 1-(2,4-dihydroxy-5-nitrophenyl)ethanone 
• 145489-91-4 4-acetyl-3-hydroxy-6-nitro-2-phenyliodonio-phenolate 

Relevant articles and documents

Hypervalent iodine oxidation of some 2,4-dihydroxyacetophenones with iodobenzene diacetate potassium hydroxide in methanol : A novel route to 2-hydroxy-3-iodo-4-phenoxyacetophenones

Hypervalent iodine oxidation of some 2,4-dihydroxyacetophenones (2a-d) with C6H5I (OAc)2 - KOH/MeOH providing a novel route to 2-hydroxy-3-iodo-4-phenoxyacetophenones (3a-d) via the rearrangement of iodonium ylides is repo

Phenyliodoniophenolates from 1,3-Dihydroxybenzene Derivatives

A new type of phenyliodonio phenolates resulting from the reaction of 1,3-dihydroxy benzene derivatives and (diacetoxyiodo)benzene were isolated and characterized.The new phenolates afforded cyclization products from their photochemical reaction with alkenes and alkynes and phenyl ethers from their thermal rearrangement.A possible reaction pathway is proposed in order to explain the regioselectivity of these reactions.