1456792-45-2

Basic information

• Product Name: (E)-6-(1-hydroxycyclohexyl)hepta-2,6-dien-4-ynyl acetate
• Synonyms: (E)-6-(1-hydroxycyclohexyl)hepta-2,6-dien-4-ynyl acetate
• CAS NO: 1456792-45-2
• Molecular Weight: 248.322
• Mol File: 1456792-45-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-6-(1-hydroxycyclohexyl)hepta-2,6-dien-4-ynyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-6-(1-hydroxycyclohexyl)hepta-2,6-dien-4-ynyl acetate(1456792-45-2)
• EPA Substance Registry System: (E)-6-(1-hydroxycyclohexyl)hepta-2,6-dien-4-ynyl acetate(1456792-45-2)

Safety Data

• Hazardous Substances Data: 1456792-45-2(Hazardous Substances Data)

Upstream product

• 591-87-7 Allyl acetate 
• 13757-08-9 1-(1-hydroxycyclohexyl)-1,3-butadiyne 

Relevant articles and documents

Regio- and stereoselectivity in the concatenated enyne cross metathesis-metallotropic [1,3]-shift of terminal 1,3-diyne This article is dedicated to Professor Paul A. Wender on the occasion of his receiving the 2012 Tetrahedron Prize for Creativity in Organic Chemistry

Enyne cross metathesis of terminal 1,3-diynes with various alkenes afforded two products of distinctive connectivity, as the result of a uniform mode of initiation but different modes of termination events with or without metallotropic [1,3]-shift. Steric and electronic factors of the substituents on the 1,3-diynes play an important role in controlling the metallotropic [1,3]-shift of the propagating alkylidene intermediates and their regioselective trapping to the final products.