14596-64-6Relevant articles and documents
Cerium metal-mediated Reformatsky-type reaction with ethyl bromosuccinate for the synthesis of novel paraconic acid analogs
Rodrigues, Shirley M. M.,Nardini, Viviani,Constantino, Mauricio G.,Da Silva, Gil Valdo J.
supporting information, p. 6136 - 6137,2 (2020/08/20)
The treatment of cerium metal with ethyl bromosuccinate (1) forms the stabilized organolanthanoid intermediate (2), which reacts with carbonyl compounds in a Reformatsky-type reaction, under mild conditions, to produce functionalized γ-substituted paraconic acids (4) in good yields.