146039-13-6

Basic information

• Product Name: (E)-3-Phenyl-allyl-phosphorimidic acid triethyl ester
• CAS NO: 146039-13-6
• Molecular Weight: 297.334
• Mol File: 146039-13-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-3-Phenyl-allyl-phosphorimidic acid triethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-Phenyl-allyl-phosphorimidic acid triethyl ester(146039-13-6)
• EPA Substance Registry System: (E)-3-Phenyl-allyl-phosphorimidic acid triethyl ester(146039-13-6)

Safety Data

• Hazardous Substances Data: 146039-13-6(Hazardous Substances Data)

Upstream product

• 57294-86-7 (3-azidoprop-1-en-1-yl)benzene 
• 122-52-1 triethyl phosphite 
• 4392-24-9 Cinnamyl bromide 

Downstream Products

• 146287-09-4 Toluene-4-sulfonic acid; compound with (E)-3-phenyl-allylamine 
• 5586-89-0 3-phenylprop-2-en-1-amine hydrochloride 
• 4360-51-4 cinnamylamine 

Relevant articles and documents

Optimized procedures for one-pot conversion of alkyl bromides into amines via the Staudinger reaction

New optimized procedures for transforming primary and secondary alkyl bromides into the corresponding primary amine salts have been elaborated. Essential modifications of azidation and deprotection of intermediate triethoxyphosphine alkylimides resulted in substantial improvement of the overall yields. Conversion of ammonium tosylates and hydrochlorides into free amines in a nonaqueous medium is described.