1464149-60-7Relevant articles and documents
Amide-Directed Bay-Region Two-Step Annulative π-Extension (APEX) of Biphenyls and Terphenyls with Diaryliodonium Salts: Efficient Access to Polycyclic Aromatic Hydrocarbons
Peng, Qiong,Zhang, Wen,Zhao, Ke,Du, Yu,Feng, Chun,Wang, Bi-Qin,Fang, Dong-Mei,Chen, Xiao-Zhen,Ni, Hai-Liang,Xiang, Shi-Kai
, p. 206 - 212 (2020)
An amide-directed bay-region two-step annulative π-extension reaction of biphenyls and terphenyls with diaryliodonium salts has been developed. A variety of polycyclic aromatic hydrocarbons can be synthesized efficiently according to this approach, such as triphenylene, dibenzo[fg,op]tetracene, and tribenzo[fg,ij,rst]pentaphene derivatives. (Figure presented.).
Catalyst-Free Arylation of Tertiary Phosphines with Diaryliodonium Salts Enabled by Visible Light
Bugaenko, Dmitry I.,Volkov, Alexey A.,Livantsov, Mikhail V.,Yurovskaya, Marina A.,Karchava, Alexander V.
supporting information, p. 12502 - 12506 (2019/09/16)
The visible-light-induced arylation of tertiary phosphines with aryl(mesityl)iodonium triflates to produce the quaternary phosphonium salts occurs under mild, metal, and catalyst-free conditions. Photo-excited EDA complexes between diaryliodonium salts an
A Modular Synthesis of 4-Aminoquinolines and [1,3] N-to-C Rearrangement to Quinolin-4-ylmethanesulfonamides
Oh, Kyung Hwan,Kim, Jin Gyeong,Park, Jin Kyoon
supporting information, p. 3994 - 3997 (2017/08/14)
A copper-catalyzed regiocontrolled three-component reaction afforded diversified 4-aminoquinolines using nitriles, diaryliodoniums, and ynamides. The C7-substituted regioisomers were formed regioselectively when meta-substituted phenyliodonium salts were used. [1,3] N-to-C rearrangement of the products to quinolin-4-ylmethanesulfonamides and simultaneous deprotection of benzyl and sulfonamide group were newly developed. Finally, antimalarial CK-2-68 was successfully prepared.
