14758-41-9

Basic information

• Product Name: 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan
• Synonyms: 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan
• CAS NO: 14758-41-9
• Molecular Weight: 446.658
• Mol File: 14758-41-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan(14758-41-9)
• EPA Substance Registry System: 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan(14758-41-9)

Safety Data

• Hazardous Substances Data: 14758-41-9(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 4832-52-4 tris(phenylthio)methane 

Downstream Products

• 14007-02-4 butyl mandelate 
• 62173-99-3 benzyl 2-hydroxy-2-phenylacetate 
• 27722-60-7 1,1,2-Tris(phenylmercapto)-2-phenyl-aethen 
• 35550-81-3 (2-phenylethene-1,1-diyl)bis(phenylsulfane) 
• 774-40-3 hydroxy-phenyl-acetic acid ethyl ester 
• 4358-87-6 (RS)-methyl mandelate 
• 4118-51-8 isopropyl mandelate 

Relevant articles and documents

Selectivities in the Reactions of Alkyl-, Aryl- and Heterosubstituted Organotitanium Compounds

Solutions of the title compounds R-Ti(OR')3 (1) are generally available from organolithium (or magnesium) derivatives according to equation 1.It is shown (table 1) that some heterosubstituted organotitanium compounds are more stable thermally than their lithium counterparts.The reagents 1 are highly selective carbonylophiles (Tables 1 and 2), their reactivity can be modified by variation of the R'O-group (Table 3) and with the chiral (S)-2-methyl-1-butoxy group an enantioselective addition can be achieved.