149195-56-2

Basic information

• Product Name: N-(2-Benzoyl-5-methyl-phenyl)-2,2,2-trifluoro-acetamide
• CAS NO: 149195-56-2
• Molecular Weight: 307.272
• Mol File: 149195-56-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-(2-Benzoyl-5-methyl-phenyl)-2,2,2-trifluoro-acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-Benzoyl-5-methyl-phenyl)-2,2,2-trifluoro-acetamide(149195-56-2)
• EPA Substance Registry System: N-(2-Benzoyl-5-methyl-phenyl)-2,2,2-trifluoro-acetamide(149195-56-2)

Safety Data

• Hazardous Substances Data: 149195-56-2(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 4937-62-6 2-amino-4-methylbenzophenone 
• 407-25-0 trifluoroacetic anhydride 
• 2305-36-4 4-methylanthranilic acid 

Downstream Products

• 149195-62-0 Methyl-<3-(S)-benzyl-8-azidomethyl-1,4-benzodiazepine-2-one>-acetate 
• 149195-63-1 Methyl-<3-(S)-benzyl-8-aminomethyl-1,4-benzodiazepine-2-one>-acetate 
• 149195-55-1 (8-Azidomethyl-2-oxo-5-phenyl-2,3-dihydro-benzo[e][1,4]diazepin-1-yl)-acetic acid ethyl ester 
• 149195-54-0 (8-Azidomethyl-2-oxo-5-phenyl-2,3-dihydro-benzo[e][1,4]diazepin-1-yl)-acetic acid methyl ester 
• 149195-60-8 3-(S)-Benzyl-8-azidomethyl-1,4-benzodiazepine-2-one 
• 149195-66-4 (8-Aminomethyl-2-oxo-5-phenyl-2,3-dihydro-benzo[e][1,4]diazepin-1-yl)-acetic acid ethyl ester 
• 149195-65-3 (8-Aminomethyl-2-oxo-5-phenyl-2,3-dihydro-benzo[e][1,4]diazepin-1-yl)-acetic acid methyl ester 
• 149195-58-4 N-(5-Azidomethyl-2-benzoyl-phenyl)-2,2,2-trifluoro-acetamide 
• 149195-61-9 8-Azidomethyl-5-phenyl-1,3-dihydro-benzo[e][1,4]diazepin-2-one 
• 149195-59-5 (2-Amino-4-azidomethyl-phenyl)-phenyl-methanone 
• 149195-57-3 N-(2-Benzoyl-5-bromomethyl-phenyl)-2,2,2-trifluoro-acetamide 

Relevant articles and documents

Asymmetric Synthesis of Hydroquinazolines Bearing C4-Tetrasubstituted Stereocenters via Kinetic Resolution of α-Tertiary Amines

A novel protocol for asymmetric synthesis of hydroquinazolines bearing C4-tetrasubstituted stereocenters has been achieved through kinetic resolution of 2-amido α-tertiary benzylamines via chiral phosphoric acid catalyzed intramolecular dehydrative cyclizations. This method gave access to both α-tertiary benzylamines and hydroquinazolines with broad scope and high enantioselectivities. An intriguing restricted rotation of the C-N bond was observed for hydroquinazoline products bearing C4-tetrasubstituted stereocenters.