1492-13-3

Basic information

• Product Name: D-Valine, N-benzoyl-, methyl ester
• CAS NO: 1492-13-3
• Molecular Formula: C13H17NO3
• Molecular Weight: 235.283
• Mol File: 1492-13-3.mol
• Article Data: 34

Chemical Properties

• CAS DataBase Reference: D-Valine, N-benzoyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: D-Valine, N-benzoyl-, methyl ester(1492-13-3)
• EPA Substance Registry System: D-Valine, N-benzoyl-, methyl ester(1492-13-3)

Safety Data

• Hazardous Substances Data: 1492-13-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 28897-81-6 2-phenyl-4-iso-propyl-4H-oxazolin-5-one 
• 5619-05-6 DL-valine methyl ester hydrochloride 
• 432550-82-8 N-benzoyl-N-ethanoylamino-2-[(S)-1-tert-butyldimethylsilyloxy-2-methylpropyl]quinazolin-4(3H)-one 
• 4070-48-8 L-Valine methyl ester 
• 100-39-0 benzyl bromide 
• 93-97-0 benzoic acid anhydride 
• 186581-53-3 diazomethane 
• 2901-80-6 (2R)-2-(benzoylamino)-3-methylbutyric acid 
• 98-88-4 benzoyl chloride 
• 516-06-3 D,L-valine 
• 2901-80-6 N-benzoyl-D,L-valine 
• 2901-80-6 N-benzoyl-L-valine 
• 479672-27-0 N-(1-formyl-2-methylpropyl)benzamide 

Downstream Products

• 78867-91-1 (2R)-2-(benzoylamino)-3-methylbutyric acid hydrazide 
• 94545-36-5 N-[(R)-2-methyl-1-(4-phenyl-thiazol-2-yl)-propyl]-benzamide 
• 93883-65-9 N-benzoyl-D-thiovaline amide 
• 874212-53-0 D-α-Benzamido-β-methylbutyronitril 
• 93883-65-9 N-benzoyl-L-thiovaline amide 
• 93732-01-5 2-((S)-1-benzoylamino-2-methyl-propyl)-thiazole-4-carboxylic acid ethyl ester 
• 874212-54-1 L-α-Benzamido-β-methylbutyronitril 
• 1452784-60-9 (2S)-2-(benzoylamino)-3-methyl-N'-(4-chlorobenzylidene)butanohydrazide 
• 1452784-61-0 (2S)-2-(benzoylamino)-3-methyl-N'-(2-chlorobenzylidene)butanohydrazide 
• 1452784-62-1 (2S)-2-(benzoylamino)-3-methyl-N'-(2,6-dichlorobenzylidene)butanohydrazide 
• 1452784-63-2 (2S)-2-(benzoylamino)-3-methyl-N'-(2,4-dichlorobenzylidene)butanohydrazide 
• 1452784-64-3 (2S)-2-(benzoylamino)-3-methyl-N'-(2-fluorobenzylidene)butanohydrazide 
• 1452784-65-4 (2S)-2-(benzoylamino)-3-methyl-N'-(3-fluorobenzylidene)butanohydrazide 
• 1452784-66-5 2-(benzoylamino)-3-methyl-N'-(4-fluorobenzylidene)butanohydrazide 

Relevant articles and documents

Green Esterification of Carboxylic Acids Promoted by tert-Butyl Nitrite

In this work, the green esterification of carboxylic acids promoted by tert-butyl nitrite has been well developed. This transformation is compatible with a broad range of substrates and exhibits excellent functional group tolerance. Various drugs and substituted amino acids are applicable to this reaction under near neutral conditions, with good to excellent yields.

Amidation of Aldehydes with Amines under Mild Conditions Using Metal-Organic Framework Derived NiO@Ni Mott-Schottky Catalyst

Here we report a facile method for the synthesis of nickel oxide-nickel (NiO@Ni) Mott-Schottky catalyst employing metal-organic framework (MOF) as the precursor. A direct amidation protocol of aldehydes with amines has been optimized under mild conditions using NiO@Ni Mott-Schottky catalyst and it shows far better catalytic activity than the NiO?Ni nanoparticles prepared from simple Ni2+ salt under similar reaction conditions. The heterogeneous catalyst is robust, recyclable and efficient to provide comparable yield to costly ligand-based homogeneous Ni catalysts. The scope of the reaction protocol has been explored with variably substituted substrates. The reaction initiates by homolytic cleavage of peroxide and proceeds through radical mechanism.

Hydrogen Bond Directed ortho-Selective C?H Borylation of Secondary Aromatic Amides

Reported is an iridium catalyst for ortho-selective C?H borylation of challenging secondary aromatic amide substrates, and the regioselectivity is controlled by hydrogen-bond interactions. The BAIPy-Ir catalyst forms three hydrogen bonds with the substrate during the crucial activation step, and allows ortho-C?H borylation with high selectivity. The catalyst displays unprecedented ortho selectivities for a wide variety of substrates that differ in electronic and steric properties, and the catalyst tolerates various functional groups. The regioselective C?H borylation catalyst is readily accessible and converts substrates on gram scale with high selectivity and conversion.