14975-23-6

Basic information

• Product Name: METHYLPHOSPHINE BORANE COMPLEX
• Synonyms: P-Methylphosphine-borane;METHYLPHOSPHINE BORANE COMPLEX;Trihydro(methylphosphine)boron(T-4)
• CAS NO: 14975-23-6
• Molecular Formula: CH₈BP
• Molecular Weight: 61.86
• Mol File: 14975-23-6.mol
• Article Data: 5

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: METHYLPHOSPHINE BORANE COMPLEX(CAS DataBase Reference)
• NIST Chemistry Reference: METHYLPHOSPHINE BORANE COMPLEX(14975-23-6)
• EPA Substance Registry System: METHYLPHOSPHINE BORANE COMPLEX(14975-23-6)

Safety Data

• Hazardous Substances Data: 14975-23-6(Hazardous Substances Data)

Usage

InChI:InChI=1/CH4BP/c1-3-2/h2H,1H3/p+1

Upstream product

• 593-54-4 methylphosphine 
• 13292-87-0 dimethylsulfide borane complex 
• 108-43-0 3-monochlorophenol 
• 585-34-2 3-tert-butylphenyol 
• 79-31-2 isobutyric Acid 
• 107-92-6 butyric acid 

Downstream Products

• 190835-96-2 H₃BPH(CH₃)CH(C₆H₅)OH 
• 190835-99-5 H₃BP(CH₃)(CH(C₆H₅)OH)2 
• 108-43-0 3-monochlorophenol 
• 103-82-2 phenylacetic acid 
• 107-92-6 butyric acid 
• 75-98-9 Trimethylacetic acid 
• 79-31-2 isobutyric Acid 
• 585-34-2 3-tert-butylphenyol 
• 593-54-4 methylphosphine 

Relevant articles and documents

The reaction of methylphosphine with carbon monoxide borane

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Synthesis, photoelectron spectroscopy and quantum chemical study of kinetically unstabilized phosphines complexed by borane

Ethynyl- and allenylphosphine-boranes have been prepared by addition at low temperature of borane on the free phosphine. Purification was performed by selective trapping in vacuo and the complexes were characterized by NMR and infrared spectroscopy and ma

P-H bond activation of primary phosphine-boranes: Access to α-hydroxy and α,α′-dihydroxyphosphine-borane adducts by uncatalyzed hydrophosphination of carbonyl derivatives

Primary P-phenyl and P-methyl phosphine-boranes 1 and 2 are prepared by complexation of the free phosphines with BH3 · SMe2. They are stable and can be purified by distillation. Under basic conditions, they lead selectively to secondary alkylphosphine-boranes and under neutral conditions to the corresponding mono- and bis-hydroxyphosphine-boranes 5 and 6. All these new compounds are purified by chromatography on silica gel. A competitive hydroboration induced by the decomplexation of BH3 is observed as a minor process. Conditions for the decomplexation of phosphine-borane adducts are presented.