151132-90-0Relevant articles and documents
Asymmetric induction in acyclic radical reactions: Enantioselective syntheses of (S)-2-deuterioglycine and (R)-2-deuterioglycine
Hamon,Massay-Westropp,Razzino
, p. 6419 - 6428 (1993)
The (-)-8-phenylmenthol esters of N-Boc-glycine and N-Boc-2,2-dideuterioglycine were brominated with N-bromosuccinimide and the bromo compounds were reduced with tri-n-butyldeuteriostannane and tri-n-butylstannane respectively, to give the chiral glycine derivatives in 90% optical yield. Hydrolysis yielded the amino acid without racemisation.