152172-45-7Relevant articles and documents
A facile 2: H -chromene dimerization through an ortho -quinone methide intermediate catalyzed by a sulfonyl derived MIL-101 MOF
Du, Xin,Li, Xiujuan,Tang, Houliang,Wang, Wenyu,Ramella, Daniele,Luan, Yi
, p. 12722 - 12728 (2018/08/04)
A MIL-101-SO3H MOF was synthesized using commercially available materials. The as-synthesized MIL-101-SO3H was characterized by SEM, XRD, FTIR, BET and TGA. An efficient and diastereoselective homo-dimerization of 2H-chromenes cataly
Acid catalyzed stereoselective rearrangement and dimerization of flavenes: synthesis of dependensin
Deodhar, Mandar,Black, David StC,Kumar, Naresh
, p. 5227 - 5235 (2008/02/01)
Appropriately substituted flavenes undergo stereoselective rearrangement and dimerization when treated with methanolic hydrochloric acid to give benzopyranobenzopyrans. A rationale for the rearrangement is proposed. This synthetic methodology has been used for a high yield synthesis of the natural product dependensin.