91856-16-5Relevant articles and documents
Structural, spectroscopic and microbiological characterization of the chalcone 2E-1-(2?-hydroxy-3?,4?,6?-trimethoxyphenyl)-3-(phenyl)-prop-2-en-1-one derived from the natural product 2-hydroxy-3,4,6-trimethoxyacetophenone
Teixeira,Santos,Bandeira,Juli?o,Freire,Lima,Cruz,da Silva,Coutinho,Sena
, p. 739 - 748 (2019)
Chalcones are important intermediates in the biosynthesis of biologically active compounds such as flavonoids and their derivatives. In this paper, a new chalcone 2E-1-(2?-Hydroxy-3?,4?,6?-trimethoxyphenyl)-3-(phenyl)-prop-2-en-1-one (HYTPHENYL) was synth
Efficient Access to Chromeno[4,3- b ]quinolines Related to Dependensin
Dobrowolski, Jeremy C.,Fraser, Benjamin H.,Bhadbhade, Mohan,Black, David Stc.,Kumar, Naresh
, p. 1979 - 1983 (2017/09/13)
We report a robust synthesis of novel chromeno[4,3- b ]quinoline derivatives structurally similar to the natural product dependensin. The target compounds are accessed through the acid-catalysed condensation of 2-aminoacetophenones or 2-aminochalcones with substituted flavanones, which are in turn obtained from 2-hydroxyacetophenones and benzaldehydes.
Acid catalyzed stereoselective rearrangement and dimerization of flavenes: synthesis of dependensin
Deodhar, Mandar,Black, David StC,Kumar, Naresh
, p. 5227 - 5235 (2008/02/01)
Appropriately substituted flavenes undergo stereoselective rearrangement and dimerization when treated with methanolic hydrochloric acid to give benzopyranobenzopyrans. A rationale for the rearrangement is proposed. This synthetic methodology has been used for a high yield synthesis of the natural product dependensin.