15225-09-9Relevant articles and documents
Characterization of carbonyl by-products during Uniblu-A ozonation by liquid chromatography/hybrid quadrupole time-of-flight/mass spectrometry
Amorisco,Locaputo,Mascolo
, p. 1801 - 1811 (2011)
The structural elucidation of carbonyl-containing by-products arising from Uniblu-OH ozonation has been investigated by liquid chromatography/electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS) employing a quadrupole time-of-flight mass spectrometer. The by-products were derivatized with 2,4-dinitrophenylhydrazine, allowing the formation of [M-H]- ions of the derivatives in the electrospray source. Exact mass measurements of both the [M-H]- ions and their product ions allowed the elemental formulae and related structures of ten by-products to be determined confidently. The main degradation pathway were decarboxylation followed by further oxidation. It is noteworthy that the experimental procedure employed allowed the identification of both nitrogen- and sulphur-containing carbonyl by-products during Uniblu-OH ozonation. This result is of environmental relevance for monitoring the balance of organic nitrogen and sulphur during the ozonation of organic pollutants. These atoms, in fact, do not undergo complete mineralization. Copyright
Influence of Nonionic Surfactant on Hydrolysis of Vinyl Sulfone Reactive Dye
Cai, Guoqiang,Sun, Liangxi,Wu, Jindan,Wang, Jiping
, p. 1127 - 1135 (2015)
Nonionic surfactants are widely used in reactive dyeing processes, and the interaction between surfactants and reactive dyes affect the hydrolytic property of reactive dyes. In this study, reactive brilliant blue KN-R (C.I. reactive blue 19) was employed