1523-89-3

Basic information

• Product Name: 2-Cyclohexene-1-carboxylic acid, 1-methyl-4-oxo-, methyl ester
• CAS NO: 1523-89-3
• Molecular Formula: C9H12O3
• Molecular Weight: 168.192
• Mol File: 1523-89-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexene-1-carboxylic acid, 1-methyl-4-oxo-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexene-1-carboxylic acid, 1-methyl-4-oxo-, methyl ester(1523-89-3)
• EPA Substance Registry System: 2-Cyclohexene-1-carboxylic acid, 1-methyl-4-oxo-, methyl ester(1523-89-3)

Safety Data

• Hazardous Substances Data: 1523-89-3(Hazardous Substances Data)

Upstream product

• 51673-64-4 methyl 2-methyl-3-oxopropanoate 
• 78-94-4 methyl vinyl ketone 
• 54125-02-9 danishefsky's diene 
• 80-62-6 methacrylic acid methyl ester 
• 127131-75-3 4-carbomethoxy-3-methoxy-4-methyl-1-<(trimethylsilyl)oxy>cyclohex-1-ene 
• 67201-24-5 methyl 1-methyl-2-trimethylsilyl-4-trimethylsilyloxycyclohex-3-enecarboxylate 
• 67201-27-8 methyl 1-methyl-4-oxo-2-trimethylsilylcyclohexanecarboxylate 
• 59414-23-2 1-methoxy-3-<(trimethylsilyl)oxy>01,3-butadiene 

Downstream Products

• 37480-41-4 methyl 1-methyl-4-oxo-1-cyclohexanecarboxylate 
• 1198227-61-0 C₁₁H₁₆O₃ 
• 1198227-75-6 C₉H₁₁IO₃ 
• 87787-20-0 2-[4-Methyl-4-(4-nitro-phenoxymethyl)-cyclohexyloxy]-tetrahydro-pyran 
• 87787-39-1 5-<4-(c-4-hydroxy-1-methyl-r-1-cyclohexylmethoxy)benzyl>-2,4-thiazolidinedione 
• 93392-66-6 5-<4-(c-4-hydroxy-1-methyl-r-1-cyclohexylmethoxy)benzyl>-2-imino-4-thiazolidinone 
• 93392-65-5 methyl 2-bromo-3-<4-(c-4-hydroxy-1-methyl-r-1-cyclohexylmethoxy)phenyl>propionate 
• 87787-14-2 4-(c-4-hydroxy-1-methyl-r-1-cyclohexylmethoxy)nitrobenzene 
• 93392-64-4 methyl 1-methyl-c-4(2-tetrahydropyranyloxy)-r-1-cyclohexanecarboxylate 
• 87787-24-4 4-(4-Amino-phenoxymethyl)-4-methyl-cyclohexanol 
• 87787-05-1 methyl c-4-hydroxy-1-methyl-r-1-cyclohexanecarboxylate 
• 87787-11-9 1-methyl-c-4-(2-tetrahydropyranyloxy)-r-1-cyclohexanemethanol 
• 87787-16-4 4-(4,4-ethylenedioxy-1-methylcyclohexylmethoxy)nitrobenzene 

Relevant articles and documents

Tandem and One-Pot Hydroformylation/Michael Reactions of Acrylates

The combination of various reactions in one operational step leads to many advantages in synthetic strategies, such as a lower consumption of resources, effort, and time, when intermittent workup and purification steps can be avoided. The hydroformylation reaction of acrylates gives access to 2-formylpropanoates, which thanks to their structural features constitute useful intermediates in the synthesis of more complex compounds. Herein, we report a simple and convenient one-pot strategy to synthesize functionalized carbonyl compounds starting from these readily available substrates, via tandem or one-pot hydroformylation, Michael addition, and aldol reactions.

Scalable synthesis of highly reactive 1,3-diamino dienes from vinamidinium salts and their use in Diels-Alder reactions

A practical and chromatography-free synthesis of vinamidinium salts and their use as diene precursors in Diels-Alder reactions is reported. Additionally, 1,3-dipyrrolidino-1,3-butadiene was shown to be significantly more reactive than Rawal's diene in a c

Efficient, Trimethylsilyl Triflate Mediated Conversion of Diels-Alder Adducts of 1-Methoxy-3--1,3-butadiene (Danishefsky's Diene) to Cyclohexenones

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