15268-07-2

Basic information

• Product Name: 3-(3-AMINOPHENOXY)ANILINE
• Synonyms: 3-(3-AMINOPHENOXY)ANILINE;3,3- DIAMINODIPHENYL ETHER(33ODA);3,3-Oxybisbenzolamine;BenzenaMine, 3,3'-oxybis-
• CAS NO: 15268-07-2
• Molecular Formula: C₁₂H₁₂N₂O
• Molecular Weight: 200.23648
• Mol File: 15268-07-2.mol
• Article Data: 8

Chemical Properties

• Melting Point: 37 °C(Solv: benzene (71-43-2); ligroine (8032-32-4))
• Boiling Point: 380.2 °C at 760 mmHg
• Flash Point: 206.1 °C
• Appearance: /
• Density: 1.216 g/cm³
• Vapor Pressure: 5.56E-06mmHg at 25°C
• Refractive Index: 1.665
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• PKA: 4.37±0.10(Predicted)
• CAS DataBase Reference: 3-(3-AMINOPHENOXY)ANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(3-AMINOPHENOXY)ANILINE(15268-07-2)
• EPA Substance Registry System: 3-(3-AMINOPHENOXY)ANILINE(15268-07-2)

Safety Data

• Hazardous Substances Data: 15268-07-2(Hazardous Substances Data)

Usage

Description

3-(3-AMINOPHENOXY)ANILINE, also known as 3,3'-Oxydianiline, is an organic compound with the molecular formula C12H11NO2. It is a derivative of aniline, featuring an amino group and a phenoxy group attached to the benzene ring. 3-(3-AMINOPHENOXY)ANILINE is known for its chemical reactivity and is commonly used as a building block in the synthesis of various organic compounds, particularly in the field of materials science.

Uses

Used in the Chemical Industry:
3-(3-AMINOPHENOXY)ANILINE is used as a reactant for the synthesis of various organic compounds, particularly in the development of new materials with unique properties. Its presence in the molecular structure allows for the formation of different chemical bonds, which can lead to the creation of novel compounds with specific characteristics.
Used in the Pharmaceutical Industry:
3-(3-AMINOPHENOXY)ANILINE is used as an intermediate in the synthesis of pharmaceutical compounds, where its unique structure can contribute to the development of new drugs with improved efficacy and reduced side effects.
Used in the Electronics Industry:
3-(3-AMINOPHENOXY)ANILINE is used as a reactant in the synthesis of a deep blue electrophosphorescent Pt(II) emitter. This application takes advantage of the compound's ability to form stable complexes with metal ions, which can exhibit unique optical properties, making it suitable for use in the development of advanced electronic devices such as organic light-emitting diodes (OLEDs) and other optoelectronic applications.

InChI:InChI=1/C12H12N2O/c13-9-3-1-5-11(7-9)15-12-6-2-4-10(14)8-12/h1-8H,13-14H2

Upstream product

• 38490-83-4 3,3'-dinitrodiphenyl ether 
• 96535-88-5 3-(3-nitro-phenoxy)-aniline 
• 591-27-5 m-Hydroxyaniline 
• 591-19-5 m-Bromoaniline 
• 554-84-7 meta-nitrophenol 
• 585-79-5 m-nitrobromobenzene 
• 3273-78-7 4-(4-amino-3-nitrophenoxy)-2-nitrophenylamine 
• 1124-31-8 potassium 4-nitrophenolate 
• 626-01-7 3-Iodoaniline 

Downstream Products

• 53357-17-8 C₁₄H₁₀N₄OS₂ 
• 6903-63-5 1-bromo-3-(3-bromophenoxy)benzene 
• 93703-48-1 3,3',4,4'-tetrabromodiphenyl ether 
• 1429922-22-4 C₄₄H₅₅N₅O₇ 
• 1429922-34-8 C₃₈H₅₀N₃O₅⁽¹⁺⁾*C₇H₇O₃S^(1-) 

Relevant articles and documents

INTRAMOLECULAR EXCHANGE COUPLING OF ARYLNITRENES BY OXYGEN

A series of m,n'-diazidodiphenyl ethers (m -1, and also showed a weak dinitrene quintet spectrum with /D/hc/=0.162 cm-1 having ESR spectral intensity vs temperature dependence (Curie law) consistent with either a high-spin ground state or a very small singlet-quintet gap.Di(3-azidophenyl) ether gave a strong mononitrene peak with /D/hc/=0.996 cm-1 and a quintet dinitrene ESR spectrum (/D/hc/=0.162 cm-1) which exhibited non-linear Curie law intensity behavior consistent with the quintet being a thermally populated excited state 40 cal mol-1 above a singlet ground state.Di(4-azidophenyl) ether gave a strong mononitrene peak with /D/hc/=0.961 cm-1, but no observable spectrum related to a high-spin open-shell dinitrene.The results are consistent with oxygen being a weak exchange coupling linker in pi-conjugated open-shell molecules.The observed ground-state spin multiplicities are in accord with qualitative superexchange and connectivity models, despite any perturbations due to resonance effects between the oxygen linker and p-nitrene sites.

Organic electroluminescent materials and devices

Novel phosphorescent platinum complexes containing tetradentate ligands are provided. The disclosed compounds have three 6-membered metallocycle units in each tertadentate ligand. The disclosed compounds have desirable electronic properties that make them useful when incorporated into a variety of OLED devices.

Orthogonal Cu- and Pd-based catalyst systems for the O- and N-arylation of aminophenols

O- or N-arylated aminophenol products constitute a common structural motif in various potentially useful therapeutic agents and/or drug candidates. We have developed a complementary set of Cu- and Pd-based catalyst systems for the selective O- and N-arylation of unprotected aminophenols using aryl halides. Selective O-arylation of 3- and 4-aminophenols is achieved with copper-catalyzed methods employing picolinic acid or CyDMEDA, trans-N,N′-dimethyl-1,2- cyclohexanediamine, respectively, as the ligand. The selective formation of N-arylated products of 3- and 4-aminophenols can be obtained with BrettPhos precatalyst, a biarylmonophosphine-based palladium catalyst. 2-Aminophenol can be selectively N-arylated with CuI, although no system for the selective O-arylation could be found. Coupling partners with diverse electronic properties and a variety of functional groups can be selectively transformed under these conditions.