153465-11-3Relevant articles and documents
Direct access to unsymmetrical tin hydrides through (hydridodiorganostannio)lithiums
Connil, Marie-Fran?oise,Jousseaume, Bernard,Pereyre, Michel
, p. 4469 - 4472 (1996)
Metalation of diorganostannanes R12SnH2 by lithium diisopropylamide afforded the corresponding (hydridodiorganostannio)lithiums, R12SnHLi, which were stable at low temperature. Further reaction with alkyl halides led to functional unsymmetrically substituted alkyldiorganostannanes, R12R2SnH. Tin hydrides with an ω-unsaturated substituent were stable at room temperature. With a 4-pentyl chain, they underwent a specific cyclization process, giving a stannacyclohexane under radical reaction conditions. A tin hydride with a tin-silicon bond could also be prepared.