7529-52-4Relevant articles and documents
Une methode simple et efficace de preparation des dihydrures organostanniques
Deleuze, H.,Maillard, B.
, p. C14 - C17 (2007/10/02)
A new and efficient method of preparation of R2SnH2 is proposed.Organodioxastannolanes were used as starting materials, these compounds being easily obtained by azeotropic distillation of water from a solution of diorganotin oxides and 1,2 diols in cyclohexane.Their reduction by commercial BH3/THF complex gave raw dialkyltin dihydrides with excellent yields and high purity degrees. Keywords: Borane; Reduction; Dialkylstannanes; 1,3-dioxa-2-stannolanes; Synthesis