154614-38-7

Basic information

• Product Name: (+/-)-N-1-acetyl-1-phenyl-2-propenylamine
• Synonyms: (+/-)-N-1-acetyl-1-phenyl-2-propenylamine
• CAS NO: 154614-38-7
• Molecular Weight: 175.23
• Mol File: 154614-38-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (+/-)-N-1-acetyl-1-phenyl-2-propenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-N-1-acetyl-1-phenyl-2-propenylamine(154614-38-7)
• EPA Substance Registry System: (+/-)-N-1-acetyl-1-phenyl-2-propenylamine(154614-38-7)

Safety Data

• Hazardous Substances Data: 154614-38-7(Hazardous Substances Data)

Upstream product

• 300-57-2 allylbenzene 
• 873-66-5 1-propenylbenzene 
• 108-21-4 Isopropyl acetate 
• 59874-90-7 N-<1-(1-phenylprop-2-enyl)> trichloroacetamide 
• 51479-71-1 O-(3-Phenyl-2-propenyl)-2,2,2-Trichlorethanimidsaeure-O-(3-phenyl-2-propenyl)ester 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 123772-66-7 N-(α-phenylpropargyl)acetamide 
• 75-24-1 trimethylaluminum 

Downstream Products

• 688362-39-2 N-[(1R)-1-phenylprop-2-en-1-yl]benzamide 
• 688362-68-7 (R)-(+)-N-acetyl-1-phenylprop-2-enylamine 
• 244092-75-9 (1S)-1-phenyl-2-propen-1-amine 
• 325490-29-7 (1R)-1-phenylprop-2-en-1-amine 
• 103150-32-9 (1S,2R)-N-1-(1-phenyl-2,3-dihydroxypropyl)benzamide 
• 14257-84-2 (R)-(-)-N-acetylphenylglycine 
• 14257-84-2 (S)-N-acetyl-2-phenylglycine 
• 4393-21-9 1-(phenyl)allylamine 

Relevant articles and documents

Rh(III) and Ir(III)Cp? Complexes Provide Complementary Regioselectivity Profiles in Intermolecular Allylic C-H Amidation Reactions

An efficient regioselective allylic C-H amidation of mono-, di-, and trisubstituted olefins has been developed. Specifically, the combination of dioxazolone reagents with RhCp? and IrCp? catalysts is reported to promote reactions with complementary regios

Intermolecular, Branch-Selective, and Redox-Neutral Cp*IrIII-Catalyzed Allylic C?H Amidation

Herein, we report the redox-neutral, intermolecular, and highly branch-selective amidation of allylic C?H bonds enabled by Cp*IrIII catalysis. A variety of readily available carboxylic acids were converted into the corresponding dioxazolones and efficiently coupled with terminal and internal olefins in high yields and selectivities. Mechanistic investigations support the formation of a nucleophilic IrIII–allyl intermediate rather than the direct insertion of an Ir–nitrenoid species into the allylic C?H bond.

Enantioselective synthesis of 1-aryl-2-propenylamines: A new approach to a stereoselective synthesis of the Taxol side chain

A variety of substituted 1-aryl-2-propenylamines of high enantiomeric purity were prepared via lipase-catalysed resolution of the corresponding racemates. (R)-1-Phenyl-2-propenylamine was further synthesised into (2R,3S)-3-benzoylamino-2-hydroxy-3-phenylpropanoic acid methyl ester, the side chain of Taxol.