155192-28-2

Basic information

• Product Name: 2,2-Diallyl-4-trimethylsilanylethynyl-4-(3-trimethylsilanyl-prop-2-ynyl)-cyclohexanone
• Synonyms: 2,2-Diallyl-4-trimethylsilanylethynyl-4-(3-trimethylsilanyl-prop-2-ynyl)-cyclohexanone
• CAS NO: 155192-28-2
• Molecular Weight: 384.709
• Mol File: 155192-28-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2-Diallyl-4-trimethylsilanylethynyl-4-(3-trimethylsilanyl-prop-2-ynyl)-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-Diallyl-4-trimethylsilanylethynyl-4-(3-trimethylsilanyl-prop-2-ynyl)-cyclohexanone(155192-28-2)
• EPA Substance Registry System: 2,2-Diallyl-4-trimethylsilanylethynyl-4-(3-trimethylsilanyl-prop-2-ynyl)-cyclohexanone(155192-28-2)

Safety Data

• Hazardous Substances Data: 155192-28-2(Hazardous Substances Data)

Upstream product

• 155192-25-9 8-Trimethylsilanylethynyl-8-(3-trimethylsilanyl-prop-2-ynyl)-1,4-dioxa-spiro[4.5]decane 
• 155192-22-6 8-Ethoxycarbonyl-8-(prop-2-ynyl)-1,4-dioxaspiro[4.5]decane 
• 155192-24-8 8-(2,2-Dibromoethenyl)-8-(prop-2-ynyl)-1,4-dioxaspiro[4.5]decane 
• 155192-23-7 8-Formyl-8-(prop-2-ynyl)-1,4-dioxaspiro[4.5]decane 
• 208248-87-7 8-Hydroxymethyl-8-(prop-2-ynyl)-1,4-dioxaspiro[4.5]decane 
• 17159-79-4 ethyl 4-oxocyclohexane-1-carboxylate 
• 1489-97-0 ethyl 1,4-dioxaspiro[4.5]decane-8-carboxylate 
• 106-95-6 allyl bromide 
• 155192-26-0 4-Trimethylsilanylethynyl-4-(3-trimethylsilanyl-prop-2-ynyl)-cyclohexanone 

Downstream Products

• 155192-30-6 2,2-Diallyl-4-ethynyl-4-prop-2-ynyl-cyclohexanone 

Relevant articles and documents

Synthetic approach to aphidicolan and stemodan basic skeletons using a "Tandem Principle" [2+2+2] and [4+2] cycloaddition reactions

A strategy based upon the "Tandem Principle" : coupling of the cobalt catalyzed [2+2+2] cycloaddition and an intramolecular [4+2] Diels-Alder reaction allowed the formation of the stemodan skeleton in 11 high yield steps starting from 4-ethoxycarbonyl cyclohexanone.