1562455-03-1

Basic information

• Product Name: [Cu(μ-Br)(3-amino-5,6-dimethyl-1,2,4-triazine)(AsPh₃)]₂
• Synonyms: [Cu(μ-Br)(3-amino-5,6-dimethyl-1,2,4-triazine)(AsPh₃)]₂
• CAS NO: 1562455-03-1
• Molecular Weight: 1147.67
• Mol File: 1562455-03-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cu(μ-Br)(3-amino-5,6-dimethyl-1,2,4-triazine)(AsPh₃)]₂(CAS DataBase Reference)
• NIST Chemistry Reference: [Cu(μ-Br)(3-amino-5,6-dimethyl-1,2,4-triazine)(AsPh₃)]₂(1562455-03-1)
• EPA Substance Registry System: [Cu(μ-Br)(3-amino-5,6-dimethyl-1,2,4-triazine)(AsPh₃)]₂(1562455-03-1)

Safety Data

• Hazardous Substances Data: 1562455-03-1(Hazardous Substances Data)

Upstream product

• 17584-12-2 5,6-dimethyl-3-amino-1,2,4-triazine 
• 603-32-7 triphenyl-arsane 
• 7787-70-4 copper(I) bromide 

Relevant articles and documents

Synthesis and structural characterization of seven copper(I) complexes with 3-amino-5,6-dimethyl-1,2,4-triazine and triphenylphosphine/triphenylarsine

Seven new copper(I) complexes containing 3-amino-5,6-dimethyl-1,2,4- triazine (ADMT), [Cu(μ-Cl)(ADMT)(PPh3)]2 (1), [Cu(μ-NCS)(ADMT)(PPh3)]2 (2), [Cu(ADMT)(PPh 3)2Cl] (3), [Cu(ADMT)(PPh3)2Br] (4), [Cu(μ-Cl)(ADMT)(AsPh3)]2 (5), [Cu(μ-Br)(ADMT) (AsPh3)]2 (6) and [Cu(ADMT)(AsPh3) 2I] (7) have been synthesized by the reactions of CuX (X = Cl, Br, I, SCN) with triphenylphosphine/triphenylarsine EPh3 (E = P for 1-4; E = As for 5-7) and ADMT in mixed solvents. Complexes 1-7 have been characterized by IR, NMR, luminescence, elemental analyses and X-ray diffraction. In 1, 2, 5 and 6, the intermolecular hydrogen bonds of type I R22(8) are formed by two N-H donors and two N atoms from two ADMT ligands. In 1-7, the intramolecular hydrogen bond of type II R11(6) is formed between one N-H donor from ADMT and one halide ion. In 1, 2, 5 and 6, the halide ions and thiocyanate ions bridge two copper atoms to form the parallelogram Cu2X2, which are further linked to form infinite zigzag chains along a-axis through the hydrogen bond of type I R2 2(8).