156301-20-1Relevant articles and documents
Direct preparation of N-diphenylphosphinoyl aziridines from 1,2-aminoalcohols utilizing nucleofugacity of diphenylphosphinates
Osborn,Osborn, Helen M. I.,Cantrill,Cantrill, Alex A.,Sweeney,Howson,Howson, William
, p. 3159 - 3162 (1994)
The improved preparation of N-diphenylphosphinoylaziridines is facilitated by the leaving group ability of the diphenylphosphinate anion.
Preparation and ring-opening reactions of N-diphenylphosphinyl aziridines
Cantrill, Alex A.,Osborn, Helen M. I.,Sweeney, Joseph
, p. 2181 - 2208 (2007/10/03)
Monochiral N-Diphenyphosphinyl aziridines ('N-Dpp azinidines') may efficiently be prepared from monochiral 2-aminoalcohols. Such aziridines undergo ring-opening reaction with a variety of nucleophiles in good yield. Dephosphinylation is accomplished under mild conditions.