156358-27-9Relevant articles and documents
A Simple Synthesis of β-Amino Sulfides
Ishibashi, Hiroyuki,Uegaki, Masayuki,Sakai, Manami
, p. 915 - 916 (1997)
Thiols reacted with 2-oxazolidinones in the presence of alkoxides to give β-amino sulfides in high yields. The method was applied to the synthesis of 5,6-dihydro-1,4-thiazin-3(2H)-ones.
Mild and selective silicon-mediated access to enantioenriched 1,2-mercaptoamines and β-amino arylchalcogenides
Tanini, Damiano,Borgogni, Cosimo,Capperucci, Antonella
supporting information, p. 6388 - 6393 (2019/04/25)
Metal-free ring opening reactions of activated and unactivated aziridines with different silyl chalcogenides are described. Judicious tuning of the reaction conditions enables the synthesis of chiral enantioenriched N-Ts and N-Boc 1,2-mercaptoamines in good yields from the corresponding aziridines and bis(trimethylsilyl)sulfide. N-Protected and N-H unactivated aziridines are efficiently converted into the corresponding β-arylchalcogeno amines upon treatment with suitable arylchalcogenosilanes. The silicon-mediated ring opening reactions proceed with excellent regioselectivity and stereospecificity, allowing to access a wide array of synthetically and biologically valuable enantioenriched chalcogenoamines.
Straightforward synthesis of non-natural selenium containing amino acid derivatives and peptides
Braga, Antonio L.,Luedtke, Diogo S.,Paixao, Marcio W.,Alberto, Eduardo E.,Stefani, Helio A.,Juliano, Luiz
, p. 4260 - 4264 (2007/10/03)
A series of non-natural selenium-containing amino acid derivatives and peptides have been synthesized, in a flexible and modular strategy. The peptide coupling reaction between N-protected amino acids and chiral ss-seleno amines afforded the desired products in high yields. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.