158419-31-9

Basic information

• Product Name: menthyl N-<1-tert-butyldimethylsilyl-2-azetidinone-4-carboxy>glycinate
• Synonyms: menthyl N-<1-tert-butyldimethylsilyl-2-azetidinone-4-carboxy>glycinate
• CAS NO: 158419-31-9
• Molecular Weight: 424.656
• Mol File: 158419-31-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: menthyl N-<1-tert-butyldimethylsilyl-2-azetidinone-4-carboxy>glycinate(CAS DataBase Reference)
• NIST Chemistry Reference: menthyl N-<1-tert-butyldimethylsilyl-2-azetidinone-4-carboxy>glycinate(158419-31-9)
• EPA Substance Registry System: menthyl N-<1-tert-butyldimethylsilyl-2-azetidinone-4-carboxy>glycinate(158419-31-9)

Safety Data

• Hazardous Substances Data: 158419-31-9(Hazardous Substances Data)

Upstream product

• 158419-36-4 menthyl Cbz-glycinate 
• 82938-49-6 benzyl (S)-1-(tert-butyldimethylsilyl)-4-oxoazetidine-2-carboxylate 
• 2216-51-5 (-)-menthol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 63254-60-4 (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 2-aminoacetate 
• 82938-50-9 (4S)-N-tert-butyldimethylsilylazetidin-2-one-4-carboxylic acid 

Relevant articles and documents

Studies on the Alkylation of Dipeptide Substrates

Alkylation of anions derived from dipeptides with a glycine at the C-terminus have been investigated.A hydrocarbon sedition in the N-terminal residue does impart some asymmetric induction.The use of a chiral ester derivative provides the potential for double asymmetric induction and good selectivity.With an aspartyl residue at the N-terminus, problems were encountered due to competing side reactions.The use of an azetidione could circumvent some of these, but the observed induction was not high.