15848-07-4Relevant articles and documents
Regioselective 1,3-dipolar cycloadditions of a 'thiocarbonyl-methanide' ((alkylidenesalfonio)methanide) with aromatic sulfines
Mloston, Grzegorz,Linden, Anthony,Heimgartner, Heinz
, p. 31 - 40 (1996)
Reaction of the spirocyclic 2,5-dihydro-1,3,4-thiadiazole 7 and thiobenzophenone S-oxide (6a) in THF at 45° yielded the spirocyclic 1,3-dithiolane 1-oxide 8, thiirane 9, and the diazane derivative 10 in a ratio of 61:15:23 (Scheme 2) The formation of 8 is
A convenient preparation of sulfines (R2C=S=O) from thioketones
Huang, Ruili,Espenson, James H.
, p. 6935 - 6936 (2007/10/03)
-
Matrix isolation of diphenylsulfene and diphenyl-α-sultine
Sander, Wolfram,Kirschfeld, Andreas,Halupka, Martin
, p. 981 - 986 (2007/10/03)
Diphenylsulfene (5) and diphenyl-α-sultine 6 were generated in cryogenic matrices by three independent routes: (i) the thermal reaction of diphenylcarbene (8) and SO2, (ii) the photochemically induced hetero Wolff rearrangement of sulfonylcarbe