15866-31-6

Basic information

• Product Name: Benzene, 1-ethenyl-4-(phenylmethyl)-
• Synonyms: 4-benzylstyrene;1-benzyl-4-vinyl-benzene;1-Benzyl-4-vinyl-benzol;4-Vinyldiphenylmethan;phenyl (4-styryl) methane;Benzene,1-ethenyl-4-(phenylmethyl)
• CAS NO: 15866-31-6
• Molecular Formula: C15H14
• Molecular Weight: 194.276
• Mol File: 15866-31-6.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 76-78 °C(Press: 0.06 Torr)
• Density: 1.0011 g/cm3
• CAS DataBase Reference: Benzene, 1-ethenyl-4-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-ethenyl-4-(phenylmethyl)-(15866-31-6)
• EPA Substance Registry System: Benzene, 1-ethenyl-4-(phenylmethyl)-(15866-31-6)

Safety Data

• Hazardous Substances Data: 15866-31-6(Hazardous Substances Data)

Upstream product

• 65189-90-4 4-(1-hydroxyethyl)benzophenone 
• 100-42-5 styrene 
• 28867-76-7 benzaldehyde benzylidenehydrazone 
• 67468-65-9 4-benzylbenzaldehyde 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 22746-83-4 4-benzylbenzoyl chloride 
• 620-86-0 4-Benzylbenzoic acid 
• 101-81-5 Diphenylmethane 
• 782-92-3 1-(4-benzylphenyl)ethanone 
• 1592-20-7 4-Vinylbenzyl chloride 
• 16635-23-7 phenyltriisopropoxytitanium(IV) 
• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 1078-58-6 diphenylzinc 
• 1024-41-5 benzyl tosylate 

Downstream Products

• 620-85-9 1-benzyl-4-ethylbenzene 
• 1026893-20-8 3-(4-benzyl-phenyl)-2,2-dichloro-cyclobutanone 

Relevant articles and documents

Nickel-Catalyzed Electrochemical C(sp3)?C(sp2) Cross-Coupling Reactions of Benzyl Trifluoroborate and Organic Halides**

Reported here is the redox neutral electrochemical C(sp2)?C(sp3) cross-coupling reaction of bench-stable aryl halides or β-bromostyrene (electrophiles) and benzylic trifluoroborates (nucleophiles) using nonprecious, bench-stable NiCl2?glyme/polypyridine catalysts in an undivided cell configuration under ambient conditions. The broad reaction scope and good yields of the Ni-catalyzed electrochemical coupling reactions were confirmed by 50 examples of aryl/β-styrenyl chloride/bromide and benzylic trifluoroborates. Potential applications were demonstrated by electrosynthesis and late-stage functionalization of pharmaceuticals and natural amino acid modification, and three reactions were run on gram-scale in a flow-cell electrolyzer. The electrochemical C?C cross-coupling reactions proceed through an unconventional radical transmetalation mechanism. This method is highly productive and expected to find wide-spread applications in organic synthesis.

Photo-Ni-Dual-Catalytic C(sp2)-C(sp3) Cross-Coupling Reactions with Mesoporous Graphitic Carbon Nitride as a Heterogeneous Organic Semiconductor Photocatalyst

The synergistic combination of a heterogeneous organic semiconductor mesoporous graphitic carbon nitride (mpg-CN) and a homogeneous nickel catalyst with visible-light irradiation at room temperature affords the C(sp2)-C(sp3) cross-co

Direct C(sp2)-C(sp3) cross-coupling of diaryl zinc reagents with benzylic, primary, secondary, and tertiary alkyl halides

The direct C(sp2)-C(sp3) cross-coupling of diaryl zinc reagents with benzylic, primary, secondary, and tertiary alkyl halides proceeded in the absence of coordinating ethereal solvents at ambient temperature without the addition of a catalyst. The C(sp2)-C(sp3) cross-coupling showed excellent functional-group tolerance, and products were isolated in high yields, generally without the requirement for purification by chromatography. This process represents an expedient, operationally simple method for the construction of new C(sp2)-C(sp3) bonds. Zinc and you'll miss it. Direct C(sp2)-C(sp3) cross-coupling of diaryl zinc reagents with alkyl halides proceeded rapidly at ambient temperature without a coordinating ethereal solvent or an added catalyst (see scheme). This versatile, operationally simple approach to C(sp2)-C(sp3) bond formation enables the expedient construction of a diverse array of carbon-based structural motifs.