1609693-05-1Relevant articles and documents
Sp3C-H bond alkylation of ketones with alkenes via ruthenium(ii) catalysed dehydrogenation of alcohols
Li, Bin,Darcel, Christophe,Dixneuf, Pierre H.
, p. 5970 - 5972 (2014/05/20)
The sp3C-H bond functionalisation of 2-pyridyl ethanols upon reaction with alkenes, in the presence of a [RuCl2(arene)] 2 catalyst and Cu(OAc)2·H2O, is performed under mild conditions without additional base. This reaction proceeds via a tandem alcohol dehydrogenation/alkylation with alkenes of the resulting ketone at its α sp3C-H bond. the Partner Organisations 2014.