1613-92-9

Basic information

• Product Name: Benzenamine, 4-methyl-N-(phenylmethylene)-, (E)-
• CAS NO: 1613-92-9
• Molecular Formula: C14H13N
• Molecular Weight: 195.264
• Mol File: 1613-92-9.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-methyl-N-(phenylmethylene)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-methyl-N-(phenylmethylene)-, (E)-(1613-92-9)
• EPA Substance Registry System: Benzenamine, 4-methyl-N-(phenylmethylene)-, (E)-(1613-92-9)

Safety Data

• Hazardous Substances Data: 1613-92-9(Hazardous Substances Data)

Upstream product

• 56644-01-0 1,2-Di-(p-toluidino)-1,2-diphenylethan 
• 2101-86-2 p-methylazidobenzene 
• 108-88-3 toluene 
• 106-49-0 p-toluidine 
• 100-51-6 benzyl alcohol 
• 99-99-0 1-methyl-4-nitrobenzene 
• 123-91-1 1,4-dioxane 
• 100-52-7 benzaldehyde 
• 100-46-9 benzylamine 
• 5405-15-2 N-benzyl-N-(4-methylphenyl)amine 
• 6852-58-0 (E)-N-benzylidene-2-methylpropan-2-amine 
• 19064-77-8 C-phenyl-N-p-tolyl-nitrone 
• 536-74-3 phenylacetylene 

Downstream Products

• 37552-67-3 3r,4t-diphenyl-1-p-tolyl-azetidin-2-one 
• 13471-34-6 N,N'-di-p-tolylbenzamidine 
• 1859-00-3 N-(4-methylphenyl)benzamidine 
• 27549-67-3 meso-N,N'-bis(4-methylphenyl)-1,2-diphenyl-1,4-ethanediamine 
• 27549-67-3 dl-N,N'-bis(4-methylphenyl)-1,2-diphenyl-1,4-ethanediamine 
• 144221-32-9 2,3-dihydro-3-(4-methylphenyl)-2-phenylbenzoquinazolin-4(1H)-one 
• 92540-81-3 2-Benzenesulfinyl-3-phenyl-1-p-tolyl-aziridine 
• 97350-99-7 threo N-p-tolyl-2-methyl-1-phenyl-3-butenylamine 
• 97350-99-7 erythro N-p-tolyl-2-methyl-1-phenyl-3-butenylamine 
• 56644-01-0 1,2-Di-(p-toluidino)-1,2-diphenylethan 
• 128220-36-0 6-methyl-2-phenyl-quinoline-4-carbonitrile 
• 80221-77-8 methyl 6-methyl-2-phenylquinoline-4-carboxylate 
• 73402-92-3 2,4-diphenyl-6-methylquinoline 
• 87797-61-3 7-methyl-2,4-diphenylquinoline 

Relevant articles and documents

Designed pincer ligand supported Co(ii)-based catalysts for dehydrogenative activation of alcohols: Studies onN-alkylation of amines, α-alkylation of ketones and synthesis of quinolines

Base-metal catalystsCo1,Co2andCo3were synthesized from designed pincer ligandsL1,L2andL3having NNN donor atoms respectively.Co1,Co2andCo3were characterized by IR, UV-Vis. and ESI-MS spectroscopic studies. Single crystal X-ray diffraction studies were investigated to authenticate the molecular structures ofCo1andCo3. CatalystsCo1,Co2andCo3were utilized to study the dehydrogenative activation of alcohols forN-alkylation of amines, α-alkylation of ketones and synthesis of quinolines. Under optimized reaction conditions, a broad range of substrates including alcohols, anilines and ketones were exploited. A series of control experiments forN-alkylation of amines, α-alkylation of ketones and synthesis of quinolines were examined to understand the reaction pathway. ESI-MS spectral studies were investigated to characterize cobalt-alkoxide and cobalt-hydride intermediates. Reduction of styrene by evolved hydrogen gas during the reaction was investigated to authenticate the dehydrogenative nature of the catalysts. Probable reaction pathways were proposed forN-alkylation of amines, α-alkylation of ketones and synthesis of quinolines on the basis of control experiments and detection of reaction intermediates.

Ruthenium N-Heterocyclic Carbene Complexes for Chemoselective Reduction of Imines and Reductive Amination of Aldehydes and Ketones

Chemoselective reduction of imines to secondary amines is catalyzed efficiently by tethered and untethered, half-sandwich ruthenium N-heterocyclic carbene (NHC) complexes at room temperature. The untethered Ru-NHC complexes are more efficient as catalysts for the reduction of aldimines and ketimines than the tethered complexes. Using the best untethered complex as a catalyst, electronic and steric demands on the reaction was probed using a series of imines. Chemoselectivity of the catalyst towards imine reduction was tested by performing inter and intramolecular competitive reactions in a variety of ways. The catalyst exhibits a very high TON and TOF under anaerobic conditions.

Synergistic Photoredox Catalysis and Organocatalysis for Inverse Hydroboration of Imines

The first catalytic inverse hydroboration of imines with N-heterocyclic carbene (NHC) boranes has been realized by means of cooperative organocatalysis and photocatalysis. This catalytic combination provides a promising platform for promoting NHC-boryl radical chemistry under sustainable and radical-initiator-free conditions. The highly important functional-group compatibility and possible application in late-stage hydroborations represent an important step forward to an enhanced α-amino organoboron library.