1621424-09-6Relevant articles and documents
Palladium-Catalyzed C-H Monoalkoxylation of α,β-Unsaturated Carbonyl Compounds
Monguchi, Yasunari,Kunishima, Kouki,Hattori, Tomohiro,Takahashi, Tohru,Shishido, Yuko,Sawama, Yoshinari,Sajiki, Hironao
, p. 3994 - 3997 (2016)
An efficient method for the direct introduction of alkoxy groups into the β-position of alkene moieties of various α,β-unsaturated carbonyl compounds through the palladium-catalyzed C(sp2)-H monoalkoxylation using alcohols in the presence of sodium nitrite was developed; the corresponding enol ethers were selectively synthesized with minimal generation of acetals.
