1631136-30-5

Basic information

• Product Name: C₂₉H₃₂N₂O₂
• Synonyms: C₂₉H₃₂N₂O₂
• CAS NO: 1631136-30-5
• Molecular Weight: 440.585
• Mol File: 1631136-30-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₉H₃₂N₂O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₉H₃₂N₂O₂(1631136-30-5)
• EPA Substance Registry System: C₂₉H₃₂N₂O₂(1631136-30-5)

Safety Data

• Hazardous Substances Data: 1631136-30-5(Hazardous Substances Data)

Upstream product

• 3189-22-8 7-methoxy-1H-indole 
• 100-39-0 benzyl bromide 
• 2436-04-6 2-(7-methoxy-indol-3-yl)-ethylamine 
• 16990-42-4 3-(2-nitrovinyl)-7-methoxy-1H-indole 
• 109021-59-2 7-methoxy-1H-indole-3-carbaldehyde 

Relevant articles and documents

Chiral anion phase transfer of aryldiazonium cations: An enantioselective synthesis of C3-diazenated pyrroloindolines

Herein is reported the first asymmetric utilization of aryldiazonium cations as a source of electrophilic nitrogen. This is achieved through a chiral anion phase-transfer pyrroloindolinization reaction that forms C3-diazenated pyrroloindolines from simple tryptamines and aryldiazonium tetrafluoroborates. The title compounds are obtained in up to 99% yield and 96% ee. The air- and water-tolerant reaction allows electronic and steric diversity of the aryldiazonium electrophile and the tryptamine core. Live and let diazene: Chiral anion phase transfer of aryldiazonium cations has been utilized to prepare C3-diazenated pyrroloindolines. The air- and water-tolerant reaction allows electronic and steric diversity in the aryldiazonium electrophile and the tryptamine core, with the products being obtained in up to 99% yield and 96% ee (MTBE=methyl tert-butyl ether).