165035-05-2

Basic information

• Product Name: methyl (3,5-dioxo-4-azatricyclo[5.2.1.0~2,6~]dec-8-en-4-yl)acetate
• Synonyms: methyl (3,5-dioxo-4-azatricyclo[5.2.1.0~2,6~]dec-8-en-4-yl)acetate
• CAS NO: 165035-05-2
• Molecular Formula: C₁₂H₁₃NO₄
• Molecular Weight: 235.23592
• Mol File: 165035-05-2.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: methyl (3,5-dioxo-4-azatricyclo[5.2.1.0~2,6~]dec-8-en-4-yl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (3,5-dioxo-4-azatricyclo[5.2.1.0~2,6~]dec-8-en-4-yl)acetate(165035-05-2)
• EPA Substance Registry System: methyl (3,5-dioxo-4-azatricyclo[5.2.1.0~2,6~]dec-8-en-4-yl)acetate(165035-05-2)

Safety Data

• Hazardous Substances Data: 165035-05-2(Hazardous Substances Data)

Upstream product

• 5680-79-5 glycine ethyl ester hydrochloride 
• 129-64-6 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride 
• 67-56-1 methanol 
• 165035-09-6 2-(1,3-dioxo-1,3,3a,4,7,7a-hexahydro-2H-4,7-methanoisoindol-2-yl)acetic acid 
• 542-92-7 cyclopenta-1,3-diene 
• 164025-07-4 (2,5-dioxo-2,5-dihydro-pyrrol-1-yl)acetic acid methyl ester 
• 70802-41-4 (Z)-N-(3-carboxy-1-oxo-2-propenyl)-glycine methyl ester 

Relevant articles and documents

Synthesis and some reactions of bicyclo[2.21]hept-2-ene-endo,endo-5,6- dicarboximidoacetic acid azide

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Features of reactions between (3,5-dioxo-4-azatricyclo-[5.2.1.0 2-endo,6-endo ]dec-8-en-4-yl)carboxylic acids and p-nitrophenyl azide

Reactions were performed of (3,5-dioxo-4-azatricyclo[5.2.1.0 2-endo,6-endo ]dec-8-en-4-yl)carboxylic acids and their derivatives with p-nitrophenyl azide. A significant fact of the involvement of the carboxy group into the formation of aziridine ring was established and the intermolecular character of this process was confirmed. The structure of compounds synthesized was proved by IR and 1H NMR spectra.

The synthesis of N-norbornenyl-amino acids and esters: Monomers for the preparation of well defined polymers

Two routes to the synthesis of various norbornene containing amino acid derivatives are described. The methodology also allows the preparation of the 7-oxonorbornene analogues, and a kinetics study of the racemisation of one of the monomers is reported.