166104-60-5

Basic information

• Product Name: [Fe(SC₆H₂(CH₃)3)2((C₆H₅)2PCH₃)2]*C₇H₈
• CAS NO: 166104-60-5
• Molecular Weight: 850.932
• Mol File: 166104-60-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Fe(SC₆H₂(CH₃)3)2((C₆H₅)2PCH₃)2]*C₇H₈(CAS DataBase Reference)
• NIST Chemistry Reference: [Fe(SC₆H₂(CH₃)3)2((C₆H₅)2PCH₃)2]*C₇H₈(166104-60-5)
• EPA Substance Registry System: [Fe(SC₆H₂(CH₃)3)2((C₆H₅)2PCH₃)2]*C₇H₈(166104-60-5)

Safety Data

• Hazardous Substances Data: 166104-60-5(Hazardous Substances Data)

Upstream product

• 1541-10-2 mesitylthiol 
• 14760-22-6 iron(II) bis(trimethylsilyl)amide 
• 1486-28-8 diphenyl(methyl)phosphine 

Relevant articles and documents

Iron(II) Phosphane Complexes. Synthesis and Crystal Structures of [Fe2I4(dppe)2], [Fe2(SR)4(dppe)2], [Fe(SR')2(dppp)] and [Fe(SR)2(PMePh2)2] (dppe=Ph2P(CH2)2PPh2; dppp=Ph2P(CH2)3PPh2; R=2,4,6-Me3C6H2; R'=2,4-tBuC6H3)

The title compounds were isolated and their structures determined by crystallographic methods. [Fe2I4(dppe)2] (1) and [Fe2(SR)4(dppe)2] (2) formdimeric complexes with the bidentate phosphane binding to different iro n atoms. The resulting ten-membered rings of both compounds exhibit a nearly identical conformation. The central FeS2P2 units of the mononuclearcomplexes [Fe(SR')2(dppp)2] (3) and [Fe(SR)2(PMePh2)2] (4) show like 2 large deviations from ideal C2v symmetry with bonding angles around the central iron atom ranging from 97.2, 92.5, and 96.5° (angle P-Fe- P in 2, 3, and 4, respectively) to 129.0, 129.9, and 133.6° (angle S-Fe-S in 2, 3, and 4, respectively).