14760-22-6

Basic information

• Product Name: Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, iron(2+) salt
• CAS NO: 14760-22-6
• Molecular Formula: C6H19NSi2.1/2Fe
• Molecular Weight: 376.62
• Mol File: 14760-22-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, iron(2+) salt(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, iron(2+) salt(14760-22-6)
• EPA Substance Registry System: Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, iron(2+) salt(14760-22-6)

Safety Data

• Hazardous Substances Data: 14760-22-6(Hazardous Substances Data)

Upstream product

• 1000850-00-9 iron(II) bis[(2-pyridylmethyl)(tert-butyldimethylsilyl)amide] 
• 55147-78-9 bis(bis(trimethylsilyl)amido)tin(II) 
• 70317-91-8 FeBr₂*2THF 
• 4039-32-1 lithium hexamethyldisilazane 

Downstream Products

• 161727-97-5 [Fe₃(SC₆H₂-2,4,6-(i-Pr)3)4(N(SiMe₃)2)2] 
• 166104-58-1 [Fe(SC₆H₃(C(CH₃)3)2)2((C₆H₅)2PCH₂)2CH₂] 
• 166104-60-5 [Fe(SC₆H₂(CH₃)3)2((C₆H₅)2PCH₃)2]*C₇H₈ 
• 849407-24-5 Fe₂S₂(N(SiMe₃)2)2(tetramethylthiourea)2 
• 22999-67-3 tris[bis(trimethylsilyl)amido]iron(III) 
• 849407-23-4 Fe₄S₄{N(SiMe₃)2}4 
• 956243-39-3 [(2,4,6-tri(isopropyl)phenyl-S)Fe]2(μ-2,6-di-p-tolylbenzenethiolate)2 
• 956243-47-3 [Fe(2,6-di-(xylyl)benzenethiolate)2] 
• 12126-50-0 bis(pentamethylcyclopentadienyl)iron(II) 
• 253150-42-4 [Fe2(μ-mesitylthiolate)2(bis(trimethylsilyl)amide)2(tetrahydrofuran)2] 
• 1018810-30-4 [Fe2(μ2-p-tolylthilato)2(bis(trimethylsilyl)amido)2(THF)2] 

Relevant articles and documents

Monomeric homoleptic (2-pyridylmethyl)(tert-butyldimethylsilyl)amido complexes of the divalent metals Mg, Mn, Fe, Co, and Zn

The transamination reaction of M[N(SiMe3)2] 2 with (2-pyridylmethyl)(tert-butyldimethylsilyl)amine yields the corresponding homoleptic metal bis[(2-pyridylmethyl)(tert-butyldimethylsilyl) amides] of Mg (1), Mn (2), Fe (3), Co (4) and Zn (5). All these compounds crystallize from hexane isotypic in the space group C2/c. From toluene the zinc derivative precipitates as toluene solvate 5·toluene. The molecular structures of these compounds are very similar with large NMN angles to the amide nitrogen atoms with NMN values of 148° (1) and 150° (5) for the diamagnetic compounds and 156° for the paramagnetic derivatives 2 and 3. The Co derivative 4 displays a rather small NCoN angle of 142°. Different synthetic routes have been explored for compound 3 which is also available via the metallation reaction of bis(2,4,6-trimethyl phenyl)iron with (2-pyridylmethyl)(tert-butyldimethylsilyl)amine and via the metathesis reaction of lithium (2-pyridylmethyl)(tertbutyldimethylsilyl)amide with [(thf) 2FeCl2]. In course of the metathesis reaction, an equimolar amount of lithium (2-pyridylmethyl)-(tert-butyldimethylsilyl)amide and [(thf)2FeCl2] yields heteroleptic (2-pyridylmethyl)(tert- butyldimethylsilyl)amido iron(II) chloride (6) which crystallizes as a centrosymmetric dimeric molecule. The oxidative C-C coupling reaction of 5 with Sn[N(SiMe3)2]2 leads to the formation of tin(II) 1,2-bis(2-pyridyl)-1,2-bis(tert-butyldimethylsilylamido)ethane, tin metal and Zn[N(SiMe3)2]2.