849407-24-5

Basic information

• Product Name: Fe₂S₂(N(SiMe₃)2)2(tetramethylthiourea)2
• CAS NO: 849407-24-5
• Molecular Weight: 761.059
• Mol File: 849407-24-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Fe₂S₂(N(SiMe₃)2)2(tetramethylthiourea)2(CAS DataBase Reference)
• NIST Chemistry Reference: Fe₂S₂(N(SiMe₃)2)2(tetramethylthiourea)2(849407-24-5)
• EPA Substance Registry System: Fe₂S₂(N(SiMe₃)2)2(tetramethylthiourea)2(849407-24-5)

Safety Data

• Hazardous Substances Data: 849407-24-5(Hazardous Substances Data)

Upstream product

• 14760-22-6 iron(II) bis(trimethylsilyl)amide 
• 2782-91-4 1,1,3,3-tetramethyl-2-thiourea 
• 7704-34-9 sulfur 

Relevant articles and documents

Synthesis of [2Fe-2S] and [4Fe-4S] clusters having terminal amide ligands from an iron(II) amide complex

The reaction of iron(II) bis-amide Fe{N(SiMe3)2} 2 with elemental sulfur afforded a direct entry to new [Fe 2S2] and [Fe2S4] clusters with terminal amide groups, Fe4S4{N(SiMe3) 2}4 (1) and Fe2S2{N(SiMe 3)2}2(tmtu)2 (2), whose structures have been determined by X-ray crystallography. Tetrameric cubane cluster 1 exhibits one reversible and one quasireversible processes in the cyclic voltammetry, whereas dimeric rhombus complex 2 reveals one irreversible reduction process. Copyright