16812-83-2Relevant articles and documents
A flexible route toward polypropylene model compounds of various tacticities
Drooghaag, Xavier,Henry, Gatan,Marchand-Brynaert, Jacqueline
, p. 3755 - 3760 (2010)
This paper reports the flexible synthesis of 2,4,6,8,10-pentamethylundecane (PMU) as well as a chromatographic method for the separation of its diastereoisomers. This strategy offers a unique opportunity to accede to three model compounds of polypropylene (PP) of different tacticities (i.e., isotactic, syndiotactic, and atactic PP). Georg Thieme Verlag Stuttgart.
An entry to non-racemic β-tertiary-β-amino alcohols, building blocks for the synthesis of aziridine, piperazine, and morpholine scaffolds
Narczyk, Aleksandra,Stecko, Sebastian
supporting information, p. 5972 - 5981 (2020/08/21)
A method for the preparation of enantiopure β-tert-amino alcohols bearing a tetrasubstituted C-stereocenter, as well as their conversion into selected medicinally privileged heterocyclic systems (morpholines, aziridines, piperazines) is reported. These co
Esterase-mediated synthesis of optically active GABA analogues containing a stereogenic all-carbon quaternary carbon atom
Felluga, Fulvia,Ghelfi, Franco,Pitacco, Giuliana,Roncaglia, Fabrizio,Valentin, Ennio,Venneri, Cesare Daniele
experimental part, p. 2183 - 2191 (2010/10/03)
Esterase from Horse Liver (HLAP) was able to hydrolyze a series of linear and cyclic β,β-dialkyl-γ-nitroesters, in spite of the well-known reluctance of hydrolytic enzymes to recognize and transform hindered substrates, such as those possessing a stereoge
