16821-61-7Relevant articles and documents
SN1 reactions with inverse rate profiles
Denegri, Bernard,Minegishi, Shinya,Kronja, Olga,Mayr, Herbert
, p. 2302 - 2305 (2007/10/03)
Carbocations may accumulate during solvolysis reactions! The fact that fast ionization followed by slow trapping of the carbocation R+ is a characteristic pattern of many solvolysis reactions requires that the generally accepted energy profiles of these reactions be revised.