16823-63-5

Basic information

• Product Name: Phenylhexyl sulfone
• Synonyms: Hexylphenyl sulfone;Phenylhexyl sulfone
• CAS NO: 16823-63-5
• Molecular Formula: C₁₂H₁₈O₂S
• Molecular Weight: 226.34
• Mol File: 16823-63-5.mol
• Article Data: 17

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Phenylhexyl sulfone(CAS DataBase Reference)
• NIST Chemistry Reference: Phenylhexyl sulfone(16823-63-5)
• EPA Substance Registry System: Phenylhexyl sulfone(16823-63-5)

Safety Data

• Hazardous Substances Data: 16823-63-5(Hazardous Substances Data)

Upstream product

• 111-25-1 1-bromo-hexane 
• 873-55-2 sodium benzenesulfonate 
• 542-69-8 1-iodo-butane 
• 5535-48-8 PVS 
• 543-63-5 n-butylmercuric chloride 
• 544-10-5 1-Chlorohexane 
• 64168-52-1 4'-nitrobenzenesulfenanilide 
• 693-02-7 hex-1-yne 
• 120915-24-4 (E)-2-bromo-1-(phenylthio)hex-1-ene 
• 111-26-2 hexan-1-amine 
• 108-98-5 thiophenol 
• 943-78-2 hexyl phenyl sulfide 
• 963-16-6 (E)-1,2-bis(phenylsulfonyl)ethylene 
• 638-45-9 1-Iodohexane 

Downstream Products

• 18409-17-1 (E)-oct-2-en-1-ol 
• 26001-58-1 (Z)-oct-2-en-1-ol 
• 42134-55-4 3-cyclohexyl-2-propen-1-ol 
• 88703-52-0 5-(Phenylsulfonyl)-2-hydroxydecan-4-on 
• 74420-32-9 5-(Phenylsulfonyl)-1-hydroxydecan-4-one 
• 91787-21-2 (1-Benzenesulfonyl-hexyl)-trimethyl-silane 
• 88703-49-5 4-(Phenylsulfonyl)-1-hydroxynonan-3-one 
• 74420-34-1 2-methyl-2-(4-phenylsulfonyl-3-oxononyl)-1,3-dioxolane 
• 111872-69-6 5-Benzenesulfonyl-4-hydroxy-1-piperidin-1-yl-decan-1-one 
• 148311-96-0 1-hydroxy-3-phenylsulphonyl-1-(triphenylsilyl)-octane 
• 943-78-2 hexyl phenyl sulfide 
• 66-25-1 hexanal 
• 74420-31-8 6-(Phenylsulfonyl)-2-hydroxyundecan-5-one 
• 1595-03-5 1-hexyl-3-methylbenzene 

Relevant articles and documents

Aryl Radical-Mediated Alkenylation of Alkyl Halides

The free-radical alkenylation of a range of alkyl iodides with a vinyldisulfones has been carried out, leading to the desired vinylsulfones in moderate to good yields under mild conditions. The process is initiated by an aryl radical which abstracts the iodine atom from the alkyl iodide to form a C-centered radical intermediate, the addition of which onto the vinyldisulfone providing the final vinylsulfone. The aryl radical is generated in situ through a single-electron transfer from an electron donor-acceptor complex (EDA) formed between a diaryliodonium salt (Ph2I+ PF6?) and triethylamine.

Alkyl radical precursor and application thereof in establishing C-C bond

The invention provides a precursor for generating an alkyl radical based on the visible light induction and a novel method for generating the radical. The alkyl sulfenamide is used as the radical precursor to generate the alkyl radical by virtue of the C-S bond cracking accelerated by the visible light, and then the alkyl radical is applied to the chemical reaction for establishing a C-C bond. Thereaction system has the characteristic of high efficiency, and has important scientific significance and application value for researching the novel C-C bond formation reaction, organic synthesis, drug synthesis and the like. In general, the invention provides a novel general method having practical application value. The thioalcohol (thioether) with rich resources is converted to a tool for derivating the alkyl radical.

Schiff base complex of Mo supported on iron oxide magnetic nanoparticles (Fe3O4) as recoverable nanocatalyst for the selective oxidation of sulfides

In this work, a new tridentate Schiff base dioxo-molybdenum(VI) complex immobilized on silica-coated magnetic nanoparticles (MoO25CML–Fe3O4@SiO2) has been synthesized and characterized using different techniques such as FTIR, TGA, AAS, ICP–AES, XRD, VSM, EDX and SEM analyses. The catalytic activity of synthesized complex was examined in the oxidation of various sulfides in the presence of H2O2 as cheap, green and eco-friendly oxidant. This catalytic system provides high conversion and selectivity toward either sulfoxides or sulfones under different conditions. Also, the nanocatalyst could be easily separated and regenerated from reaction media by external magnet and could be reused for ten times without significant loss of the activity and selectivity.