16938-99-1

Basic information

• Product Name: Carbamic acid, (2-oxopropyl)phenyl-, methyl ester
• CAS NO: 16938-99-1
• Molecular Formula: C11H13NO3
• Molecular Weight: 207.229
• Mol File: 16938-99-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Carbamic acid, (2-oxopropyl)phenyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (2-oxopropyl)phenyl-, methyl ester(16938-99-1)
• EPA Substance Registry System: Carbamic acid, (2-oxopropyl)phenyl-, methyl ester(16938-99-1)

Safety Data

• Hazardous Substances Data: 16938-99-1(Hazardous Substances Data)

Upstream product

• 25209-79-4 phenyl-carbamic acid-(β,β'-dibromo-isopropyl ester) 
• 2651-82-3 phenyl-carbamic acid-(β,β'-dichloro-isopropyl ester) 
• 124-41-4 sodium methylate 
• 112474-32-5 5-methylene-3-phenyloxazolidin-2-one 
• 15572-13-1 3-phenyl-5-methyl-4-oxazolin-2-one 
• 80311-73-5 {2-[(E)-Methylimino]-propyl}-phenyl-carbamic acid methyl ester 
• 73193-56-3 1-<(carbomethoxy)phenylamino>-2-propanol 

Downstream Products

• 73193-40-5 Acetic acid 1-[(methoxycarbonyl-phenyl-amino)-methyl]-vinyl ester 
• 73193-42-7 Acetic acid (Z)-2-(methoxycarbonyl-phenyl-amino)-1-methyl-vinyl ester 
• 73193-41-6 Acetic acid (E)-2-(methoxycarbonyl-phenyl-amino)-1-methyl-vinyl ester 
• 69101-92-4 Phenyl-(2-triethylsilanyloxy-allyl)-carbamic acid methyl ester 
• 69079-10-3 Phenyl-((Z)-2-triethylsilanyloxy-propenyl)-carbamic acid methyl ester 
• 69079-11-4 Phenyl-((E)-2-triethylsilanyloxy-propenyl)-carbamic acid methyl ester 

Relevant articles and documents

Regiospecific Introduction of Amino-alkene Functionality into 1,2,3-Triols, 1,3-Dihalogenopropan-2-ols, and 2,3-Dihalogenopropanols promoted by Fluoride Anion

Regiospecific transformations of 1,2,3-triol, 1,3-dihalogenopropan-2-ol, and 2,3-dihalogenopropanol derivatives into oxazolidin-2-ones and/or oxazol-2(3H)-ones promoted by fluoride anion are described.

Specific Enolates from α-Amino Ketones

The enolization of 11 tertiary α-amino ketones was investigated under three different conditions (kinetic base, thermodynamic base, thermodynamic acid) to determine the directionality of such enolates for application to alkaloid synthesis.The ketone structural variables examined were the geometry of the amine nitrogen lone pair-carbonyl array and the electronic nature of the nitrogen substituent.With the exception of 3-pyrrolidinones, increasing the electron-withdrawing nature of the nitrogen increases the amount of enolization toward nitrogen (3, 6, and 9 or 21, 24, and 27).N-Alkyl-substituted amino ketones (3, 12, 21, 33) under kinetic base conditions yield enolate distributions similar to those of the corresponding all-carbon compounds.N-Carbamato-substituted amino ketones (6, 24, 27, 30) enolize predominantly toward nitrogen under all conditions.The 3-pyrrolidinones 12, 15, and 18 afford enolates away from nitrogen under all conditions.