170470-64-1Relevant articles and documents
Investigation in the Chromone Series. Part XXII. Reactivity of Phosphorohydrazides with 4-oxo-4H-1-benzopyran and its Methyl Derivatives
Nawrot-Modranka, J.,Kostka, K.
, p. 1148 - 1152 (2007/10/02)
In the reaction of chromone (4-oxo-4H-1-benzopyran) (1a) with two moles of diphenylphosphorohydrazide (2) tautomeric compounds 3a and 4a were obtained.In the same conditions 6- and 8- methyl-4-oxo-4H-1-benzopyran (1b, c) forms only 4b and 4c tautomers, and the 2-methyl derivative does not react with the compound 2.Diphenylthiophosphorohydrazide (5) does not react with the studied compounds.Nucleophilic properties of N-1 and N-2 nitrogens in phosphoro- and thiophosphorohydrazide were compared with the previously studied methyl- and phenylhydrazide in the reaction with 4-oxo-4H-1-benzopyran. Key words: 3-(2-hydroxyphenyl)-1,3-bis(diphenylphosphorohydrazono)-propane, 2-diphenylphosphorohydrazino-4-diphenylphosphorohydrazono-2,3-dihydro-4H-1-benzopyran, structure, tautomerism of