170708-52-8

Basic information

• Product Name: (2R,3R,4R)-1,2-epoxy-3-methoxy-4-(4-methoxybenzyl)oxy-5-methylhexane
• Synonyms: (2R,3R,4R)-1,2-epoxy-3-methoxy-4-(4-methoxybenzyl)oxy-5-methylhexane
• CAS NO: 170708-52-8
• Molecular Weight: 280.364
• Mol File: 170708-52-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3R,4R)-1,2-epoxy-3-methoxy-4-(4-methoxybenzyl)oxy-5-methylhexane(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4R)-1,2-epoxy-3-methoxy-4-(4-methoxybenzyl)oxy-5-methylhexane(170708-52-8)
• EPA Substance Registry System: (2R,3R,4R)-1,2-epoxy-3-methoxy-4-(4-methoxybenzyl)oxy-5-methylhexane(170708-52-8)

Safety Data

• Hazardous Substances Data: 170708-52-8(Hazardous Substances Data)

Upstream product

• 189164-69-0 (E)-(R)-4-(4-Methoxy-benzyloxy)-5-methyl-hex-2-enoic acid methyl ester 
• 189164-70-3 (2R,3R,4R)-2,3-dihydroxy-4-(4-methoxybenzyl)oxy-5-methyl-1-hexanol 
• 189164-64-5 (R)-2-Methyl-6-(tetrahydro-pyran-2-yloxy)-hex-4-yn-3-ol 
• 189164-65-6 2-[(R)-4-(4-Methoxy-benzyloxy)-5-methyl-hex-2-ynyloxy]-tetrahydro-pyran 
• 189164-68-9 (R)-2-(4-Methoxy-benzyloxy)-3-methyl-butyric acid ethyl ester 
• 189164-66-7 (4R)-4-(4-methoxybenzyl)oxy-5-methyl-2-hexyne-1-ol 
• 189164-67-8 (4R,2E)-4-(p-methoxybenzyloxy)-5-methylhex-2-en-1-ol 
• 958018-56-9 (R)-2-(4-Methoxy-benzyloxy)-3-methyl-butyraldehyde 
• 189164-63-4 6-[(tetrahydro-2H-pyran-2-yl)oxy]-2-methylhex-4-yn-3-one 
• 184104-18-5 (2R)-2-(4-methoxybenzyl)oxy-3-methyl-1-butanol 
• 41056-46-6 1-isopropyl-4-(tetrahydro-2-pyranyloxy)-2-butyn-1-ol 
• 824-94-2 p-methoxybenzyl chloride 
• 129025-85-0 ethyl (R)-2-hydroxy-3-methylbutyrate 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 

Downstream Products

• 189164-76-9 (R)-4-((S)-1-{2-[(2R,3S,4R)-2-Hydroxy-3-methoxy-4-(4-methoxy-benzyloxy)-5-methyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-[1,3]dioxolan-2-one 
• 170708-55-1 (2R,3S,6R,7S,8R)-6-(t-butyldimethylsiloxy)-1,2-dihydroxy-7-methoxy-8-(4-methoxybenzyl)oxy-3,9-dimethyl-4-(1,3-dithian-2-yl)-decane 
• 170708-51-7 (2R,3S,6R,7S,8R)-6-(t-butyldimethylsiloxy)-1,2-epoxy-7-methoxy-8-(4-methoxybenzyl)oxy-3,9-dimethyl-4-(1,3-dithian-2-yl)-decane 
• 109946-35-2 tautomycin 
• 189164-74-7 (2R,3R,4R)-2-hydroxy-3-methoxy-4-(4-methoxybenzyl)oxy-5-methyl-1-hexanol 
• 189164-72-5 (2R,3S,4R)-2-hydroxy-3-methoxy-4-(4-methoxybenzyl)oxy-5-methyl-1-phenylhexane 
• 170708-54-0 (2R,3S,6R,7S,8R)-6-hydroxy-1,2-isopropylidenedioxy-7-methoxy-8-(4-methoxybenzyl)oxy-3,9-dimethyl-4-(1,3-dithian-2-yl)-decane 
• 642442-79-3 1-[2-(2-(tert-butyl-dimethyl-silanyloxy)-5-{3,9-dimethyl-8-[3-(2-methyl-[1,3]dithian-2-yl)-butyl]-1,7-dioxa-spiro[5.5]undec-2-yl}-1-methyl-hexyl)-[1,3]dithian-2-yl]-3-methoxy-4-(4-methoxy-benzyloxy)-5-methyl-hexan-2-ol 

Relevant articles and documents

Synthetic studies on tautomycin synthesis of segment B

The synthesis of Segment B corresponding to the C26-C17 portion of tautomycin was accomplished by coupling reaction between the epoxide (Sub-segment B-l) and the dithiane (Subsegment B-2). The degradation product of tautomycin corresponding to the C26-C19 portion was also synthesized from Sub-segment B-1.