189164-67-8

Basic information

• Product Name: 2-Hexen-1-ol, 4-[(4-methoxyphenyl)methoxy]-5-methyl-, (2E,4R)-
• CAS NO: 189164-67-8
• Molecular Formula: C15H22O3
• Molecular Weight: 250.338
• Mol File: 189164-67-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Hexen-1-ol, 4-[(4-methoxyphenyl)methoxy]-5-methyl-, (2E,4R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexen-1-ol, 4-[(4-methoxyphenyl)methoxy]-5-methyl-, (2E,4R)-(189164-67-8)
• EPA Substance Registry System: 2-Hexen-1-ol, 4-[(4-methoxyphenyl)methoxy]-5-methyl-, (2E,4R)-(189164-67-8)

Safety Data

• Hazardous Substances Data: 189164-67-8(Hazardous Substances Data)

Upstream product

• 189164-64-5 (R)-2-Methyl-6-(tetrahydro-pyran-2-yloxy)-hex-4-yn-3-ol 
• 189164-65-6 2-[(R)-4-(4-Methoxy-benzyloxy)-5-methyl-hex-2-ynyloxy]-tetrahydro-pyran 
• 189164-68-9 (R)-2-(4-Methoxy-benzyloxy)-3-methyl-butyric acid ethyl ester 
• 958018-56-9 (R)-2-(4-Methoxy-benzyloxy)-3-methyl-butyraldehyde 
• 189164-63-4 6-[(tetrahydro-2H-pyran-2-yl)oxy]-2-methylhex-4-yn-3-one 
• 184104-18-5 (2R)-2-(4-methoxybenzyl)oxy-3-methyl-1-butanol 
• 41056-46-6 1-isopropyl-4-(tetrahydro-2-pyranyloxy)-2-butyn-1-ol 
• 824-94-2 p-methoxybenzyl chloride 
• 129025-85-0 ethyl (R)-2-hydroxy-3-methylbutyrate 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 844494-24-2 (3S)-3-(4-methoxybenzyloxy)-2-methyl-hex-5-ene 
• 67760-85-4 (S)-2-methyl-5-hexen-3-ol 
• 844494-27-5 (4R,2E)-4-(p-methoxybenzyloxy)-5-methylhex-2-enyl acetate 
• 189164-69-0 (E)-(R)-4-(4-Methoxy-benzyloxy)-5-methyl-hex-2-enoic acid methyl ester 

Downstream Products

• 189164-70-3 (2R,3R,4R)-2,3-dihydroxy-4-(4-methoxybenzyl)oxy-5-methyl-1-hexanol 
• 170708-52-8 (2R,3R,4R)-1,2-epoxy-3-methoxy-4-(4-methoxybenzyl)oxy-5-methylhexane 
• 170708-54-0 (2R,3S,6R,7S,8R)-6-hydroxy-1,2-isopropylidenedioxy-7-methoxy-8-(4-methoxybenzyl)oxy-3,9-dimethyl-4-(1,3-dithian-2-yl)-decane 
• 170708-51-7 (2R,3S,6R,7S,8R)-6-(t-butyldimethylsiloxy)-1,2-epoxy-7-methoxy-8-(4-methoxybenzyl)oxy-3,9-dimethyl-4-(1,3-dithian-2-yl)-decane 
• 170708-55-1 (2R,3S,6R,7S,8R)-6-(t-butyldimethylsiloxy)-1,2-dihydroxy-7-methoxy-8-(4-methoxybenzyl)oxy-3,9-dimethyl-4-(1,3-dithian-2-yl)-decane 
• 189164-71-4 (2R,3R,4R)-1,2-epoxy-3-hydroxy-4-(4-methoxybenzyl)oxy-5-methylhexane 
• 189164-74-7 (2R,3R,4R)-2-hydroxy-3-methoxy-4-(4-methoxybenzyl)oxy-5-methyl-1-hexanol 
• 189164-72-5 (2R,3S,4R)-2-hydroxy-3-methoxy-4-(4-methoxybenzyl)oxy-5-methyl-1-phenylhexane 
• 189164-76-9 (R)-4-((S)-1-{2-[(2R,3S,4R)-2-Hydroxy-3-methoxy-4-(4-methoxy-benzyloxy)-5-methyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-[1,3]dioxolan-2-one 

Relevant articles and documents

Hydrocarbon oxidation vs C-C bond-forming approaches for efficient syntheses of oxygenated molecules

(Chemical Equation Presented) A hydrocarbon oxidation approach has been applied to the construction of several linear (E)-allylic alcohols that have served as intermediates in the synthesis of natural products and natural product-like molecules. In the original syntheses, these intermediates were constructed using a standard Wittig-type olefination approach. We report here that routes to these same intermediates designed around a hydrocarbon oxidation approach are more efficient both in the total number of functional group manipulations (FGMs) and overall steps, as well as in the overall yield.