17101-71-2

Basic information

• Product Name: Benzene, [(2-bromoethenyl)thio]-, (Z)-
• CAS NO: 17101-71-2
• Molecular Formula: C8H7BrS
• Molecular Weight: 215.114
• Mol File: 17101-71-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-bromoethenyl)thio]-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-bromoethenyl)thio]-, (Z)-(17101-71-2)
• EPA Substance Registry System: Benzene, [(2-bromoethenyl)thio]-, (Z)-(17101-71-2)

Safety Data

• Hazardous Substances Data: 17101-71-2(Hazardous Substances Data)

Upstream product

• 540-49-8 cis+trans-dibromoethylene 
• 108-98-5 thiophenol 
• 1822-73-7 phenylthioethylene 
• 63413-91-2 3-(phenylthio)acrylic acid 
• 598-16-3 1,1,2-tribromoethylene 
• 160661-43-8 1,2-dibromo-1-phenylsulfanyl-ethane 

Downstream Products

• 6228-98-4 phenylthioacetylene 
• 52244-26-5 cis-β-Bromovinyl phenyl sulfone 
• 75712-32-2 (Z)-dec-1-en-1-yl phenyl sulphide 
• 147609-50-5 (Z)-C₆H₅SCHCHCH₂BO₂(CMe₂)2 
• 129196-73-2 (E)-1-(2,6-Dichloro-phenyl)-4-phenylsulfanyl-2-vinyl-but-3-en-1-ol 
• 129196-73-2 (Z)-1-(2,6-Dichloro-phenyl)-4-phenylsulfanyl-2-vinyl-but-3-en-1-ol 
• 129196-75-4 (E)-1-(2,6-Dichloro-phenyl)-2-phenylsulfanyl-hexa-3,5-dien-1-ol 
• 129196-75-4 (Z)-1-(2,6-Dichloro-phenyl)-2-phenylsulfanyl-hexa-3,5-dien-1-ol 
• 129196-74-3 (3E,5E)-1-(2,6-Dichloro-phenyl)-6-phenylsulfanyl-hexa-3,5-dien-1-ol 
• 129196-72-1 (3E,5E)-1-Phenyl-6-phenylsulfanyl-hexa-3,5-dien-1-ol 
• 129196-71-0 (E)-1-Phenyl-2-phenylsulfanyl-hexa-3,5-dien-1-ol 
• 129196-70-9 1-((E)-3-Phenylsulfanyl-1-vinyl-allyl)-cyclopentanol 
• 882-33-7 diphenyldisulfane 
• 137905-48-7 (E)-1-phenylsulphenyl-3-(3-oxocyclohexyl)-1,4-pentadiene 

Relevant articles and documents

Halodecarboxylation of α,β-acetylenic and α,β-ethylenic acids

Reaction of bis(collidine)iodine(I) (or bromine (I)) hexafluorophosphate with acetylenic acids led to the corresponding iodo(or bromo)acetylenes in high yields. This halodecarboxylation reaction was also observed with acrylic acids substituted in position 3 by an aryl group or an heteroatom.

NUCLEOPHILIC REACTION AT A VINYL CENTER. XXII. SYNTHESIS AND NUCLEOPHILIC VINYLIC SUBSTITUTION IN E-β-FLUOROVINYL ARYL SULFONES

The reaction of potassium fluoride with E-β-bromovinyl aryl sulfones in the presence of 18-crown-6-ether leads to a mixture of the sulfones XC6H4SO2CH2CHF2 and E-XC6H4SO2CH=CHF, the ratio of which decreases in the order X=CH3, H, Cl, NO2.The kinetics of n

NUCLEOPHILIC REACTIONS AT VINYL CENTER. VIII. SYNTHESIS AND PROPERTIES OF β,β-DIBROMOVINYL PHENYL SULFONE

The radical reaction of tribromoethylene with thiophenol was investigated.In addition to the main product, β,β-dibromovinyl phenyl sulfide, 15-30percent (depending on the conditions) of a mixture of isomeric β-bromovinyl phenyl sulfides is formed. β,β-Dibromovinyl phenyl sulfone was obtained by the oxidation of dibromovinyl phenyl sulfide, and it readily enters into nucleophilic vinyl substitution of both bromine atoms.During comparison of its reactivity with the reactivity of the previously investigated dichlorovinyl phenyl sulfone a clearly defined "element-effect" was detected, indicating cleavage of the C-Hlg bond at the rate-determining stage.