75712-32-2Relevant articles and documents
STEREOSELECTIVE SYNTHESIS OF (E)-ALKENYLSILANES FROM ALDEHYDES WITH A REAGENT PREPARED BY CHROMIUM(II) REDUCTION OF Me3SiCHBr2
Takai, Kazuhiko,Kataoka, Yasutaka,Okazoe, Takashi,Utimoto, Kiitiro
, p. 1443 - 1446 (1987)
Aldehydes are converted to the corresponding (E)-alkenylsilanes with one carbon homologation by means of a gemdichromium reagent prepared by CrCl2 reduction of Me3SiCHBr2 in THF.Transformation of aldehydes into alkenyl sulfides is also achieved with a com
Radical Carbonylation of Alkynes in the Presence of Thiols
Nakatani, Shogo,Yoshida, Jun-ichi,Isoe, Sachihiko
, p. 880 - 881 (2007/10/02)
Treatment of alkynes with thiols under an atmosphere of carbon monoxide initiated by azobis(isobutyronitrile) (AIBN) gives β-alkylthio-α,β-unsaturated aldehydes.
A STEREOSELECTIVE ROUTE TO ALKENYL SULFIDES THROUGH THE PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF 9-ALKYL-9-BBN WITH 1-BROMO-1-PHENYLTHIOETHENE OR (E)- AND (Z)-2-BROMO-1-PHENYLTHIO-1-ALKENES
Hoshino, Yukio,Ishiyama, Tatsuo,Miyaura, Norio,Suzuki, Akira
, p. 3983 - 3986 (2007/10/02)
The reaction of 9-alkyl-9-BBNs with 1-bromo-1-phenylthioethene or (E)- and (Z)-2-bromo-1-phenylthio-1-alkenes takes place readily in the presence of Pd(PPh3)4 and sodium hydroxide to afford stereodefined vinylic sulfides in exellent yields.