5533-18-6

Basic information

• Product Name: Dichloromethylphenylsulphide
• Synonyms: Dichloromethylphenylsulphide
• CAS NO: 5533-18-6
• Molecular Formula: C₇H₆Cl₂S
• Molecular Weight: 193.09
• Mol File: 5533-18-6.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Dichloromethylphenylsulphide(CAS DataBase Reference)
• NIST Chemistry Reference: Dichloromethylphenylsulphide(5533-18-6)
• EPA Substance Registry System: Dichloromethylphenylsulphide(5533-18-6)

Safety Data

• Hazardous Substances Data: 5533-18-6(Hazardous Substances Data)

Upstream product

• 7205-91-6 phenylthiomethyl chloride 
• 100-68-5 methyl-phenyl-thioether 
• 4885-02-3 Dichloromethyl methyl ether 
• 27064-03-5 S-phenyl methanethioate 
• 701-65-5 (trichloromethylthio)benzene 
• 56-23-5 tetrachloromethane 
• 1193-82-4 racemic methyl phenyl sulfoxide 

Downstream Products

• 31540-74-6 dichloromethyl phenyl sulfone 
• 701-65-5 (trichloromethylthio)benzene 
• 75712-32-2 [((E)-Dec-1-enyl)sulfanyl]-benzene 
• 124306-21-4 E-1-chloro-2-methyl-2-trimethylsilyl-cyclopropyl phenyl sulfide 
• 124306-21-4 Z-1-chloro-2-methyl-2-trimethylsilyl-cyclopropyl phenyl sulfide 
• 124306-24-7 r-1-chloro-t-3-phenyl-c-2-trimethylsilyl-cyclopropyl phenyl sulfide 
• 124306-24-7 r-1-chloro-c-3-phenyl-t-2-trimethylsilyl-cyclopropyl phenyl sulfide 
• 124306-22-5 r-1-chloro-c-3-methyl-c-2-trimethylsilyl-cyclopropyl phenyl sulfide 
• 124306-23-6 Z-1-chloro-2-phenyl-2-trimethylsilyl-cyclopropyl phenyl sulfide 
• 72178-73-5 (1R,3S)-3-((Z)-2-Chloro-2-phenylsulfanyl-vinyl)-2,2-dimethyl-cyclopropanecarboxylic acid 
• 16619-61-7 1-phenyl-2-phenylthioethene 
• 124306-39-4 Z-1-chloro-2-(trimethylsilylmethyl)cyclopropyl phenyl sulfide 
• 124306-39-4 E-1-chloro-2-(trimethylsilylmethyl)cyclopropyl phenyl sulfide 
• 124306-22-5 r-1-chloro-t-3-methyl-c-2-trimethylsilyl-cyclopropyl phenyl sulfide 

Relevant articles and documents

Chlorination of various substrates in subcritical carbon tetrachloride

Various aliphatic hydrocarbons and the side chains of aromatic hydrocarbons were chlorinated in subcritical carbon tetrachloride. Chlorination of aromatic compounds including 1,4-disubstituted benzenes was investigated. Ketones and sulfones were stable under the employed conditions. Sulfoxides were converted into sulfides in a low to modest yields. The coupling adducts between olefins and carbon tetrachloride were obtained from the reactions of olefins.

Selectivity towards hydrodehalogenation and dehalo-coupling in the reduction of trichloromethyl derivatives with iron(II) chloride

The reductive electron transfer (ET) induced on a series of RCCl3 derivatives by iron(II) chloride has been studied.The main reaction products are the homocoupling dimer, RCCl2-CCl2R, and the H/Cl substitution derivative, RCHCl2, and the majority of the compounds examined exhibit a highly selective tendency to form just one of these products.As a general rule, the RCHCl2 compound is the main product when the R group contains substituents which make further reduction of the radical to the carbanion easier and behave as ligands towards the iron(II) ion.In the other cases, the dimer RCCl2-CCl2R is the main product.A few exceptions are found, and these are discussed in view of the possible effects of the R moiety on the different possible routes for the reaction products.The presence of unsaturated derivatives, RCCl=CClR (E/Z mixture), was observed in the case of the reactions where the homocoupling product was also obtained and is ascribed, on the basis of experimental evidence, to a dehalogenation mechanism of the dimer RCCl2-CCl2R assisted by the iron(II) ion.