171563-44-3

Basic information

• Product Name: 3'-O-acetyl-2'-O-(tert-butyldimethylsilyl)-5'-5'-phenylselenothymidine
• CAS NO: 171563-44-3
• Molecular Weight: 553.589
• Mol File: 171563-44-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3'-O-acetyl-2'-O-(tert-butyldimethylsilyl)-5'-5'-phenylselenothymidine(CAS DataBase Reference)
• NIST Chemistry Reference: 3'-O-acetyl-2'-O-(tert-butyldimethylsilyl)-5'-5'-phenylselenothymidine(171563-44-3)
• EPA Substance Registry System: 3'-O-acetyl-2'-O-(tert-butyldimethylsilyl)-5'-5'-phenylselenothymidine(171563-44-3)

Safety Data

• Hazardous Substances Data: 171563-44-3(Hazardous Substances Data)

Upstream product

• 171563-36-3 3'-O-(tert-butyldimethylsilyl)-5'-deoxy-5'-phenylselenothymidine 
• 129801-99-6 3'-O-(tert-butyldimethylsilyl)-5'-O-(p-toluenesulfonyl)thymidine 
• 1666-13-3 diphenyl diselenide 
• 108-24-7 acetic anhydride 

Relevant articles and documents

Uridine 5'-monoselenoacetals as substrates for diastereoselective homolytic C-C bond formation

Uridine 5'-monoselenoacetals prepared by the seleno-Pummere reaction of 5'-deoxy-5'-phenylselenouridines were used as substrates for radical-mediated reactions with allyltributyltin. The reaction of the 2',3'-O-isopropylidene derivative gave cyclized products, 5-allyl-6-5'-cyclonucleosides, whereas those of the 2',3'-bis-O-(tert-butyldimethylsilyl derivatives underwent the C-C bond formation at the 5'-position to give (5'S)- and (5'R)-isomers. The stereochemical outcome of both types of reactions is discussed. The use of radical acceptors other than allyltributyltin was also examined.