17177-76-3Relevant articles and documents
Method for reducing harmful and composition of herbicide chemicals for reducing agent, a reducing injury
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Paragraph 0167, (2016/10/09)
Disclosed are: a chemical damage reducing agent for a herbicide, which is capable of reducing or preventing chemical damage and reducing the burden on the environment without using a plurality of different herbicidally active ingredients in combination; a herbicidal composition which is reduced in chemical damage; and a method for reducing chemical damage on a crop. Specifically disclosed is a chemical damage reducing agent for a herbicide, which is characterized by containing a compound represented by general formula (I) (wherein R represents a C1-C4 alkyl group or a hydroxycyclohexyl group, and X represents a carboxyl group, a hydroxyl group, a carbamoyl group, a dimethylcarbamoyl group, a C1-C4 alkoxycarbonyl group or a benzyloxycarbonyl group) or a salt thereof as a main component. Also specifically disclosed is a herbicidal composition reduced in chemical damage, which is characterized by containing the above-described chemical damage reducing agent for a herbicide and one or more specific herbicidally active compounds.
Electroorganic Reactions. Part 37. The Stereochemistry and Mechanism of the Cathodic Hydrogenation of Methyl 4-tert-Butylcyclohex-1-enecarboxylate
Matteis, Cristina I. De,Utley, James H. P.
, p. 879 - 883 (2007/10/02)
Methyl 4-tert-butylcyclohex-1-enecarboxylate is hydrogenated at a mercury cathode, in the presence of proton donors, in a smooth 2 F mol-1 process.The proportions of cis and trans isomers in the product (methyl 4-tert-butylcyclohexanecarboxylate) are a function of reaction conditions and detailed consideration shows that the reaction is under kinetic control.Protonation of the first-formed radical anion is probably at C-1, with little stereoselectivity.The results of base- and radical-induced epimerizations of 1,4-disubstituted cyclohexanes were used to establishthe likely outcome of thermodynamic control.These results are in impressive agreement with calculations based on substituent group conformational preferences.
Enzymes in Organic Synthesis. 43. Investigation of the Preferred Orientations of Ester Groups in Pig Liver Esterase Catalyzed Hydrolyses Using Conformationally Rigid Substrates
Lam, Lister K. P.,Jones, J. Bryan
, p. 2637 - 2639 (2007/10/02)
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