17299-41-1

Basic information

• Product Name: 1,6,6-Trimethylcyclohexene-3-one
• Synonyms: 1,6,6-Trimethylcyclohexene-3-one;3,4,4-Trimethyl-2-cyclohexen-1-one
• CAS NO: 17299-41-1
• Molecular Formula: C₉H₁₄O
• Molecular Weight: 138.21
• Mol File: 17299-41-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 217°C (estimate)
• Flash Point: 75.7°C
• Appearance: /
• Density: 0.9440
• Vapor Pressure: 0.136mmHg at 25°C
• Refractive Index: 1.4889 (estimate)
• CAS DataBase Reference: 1,6,6-Trimethylcyclohexene-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6,6-Trimethylcyclohexene-3-one(17299-41-1)
• EPA Substance Registry System: 1,6,6-Trimethylcyclohexene-3-one(17299-41-1)

Safety Data

• Hazardous Substances Data: 17299-41-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 112, p. 1286, 1990 DOI: 10.1021/ja00159a082

InChI:InChI=1/C9H14O/c1-7-6-8(10)4-5-9(7,2)3/h6H,4-5H2,1-3H3

Upstream product

• 1727-75-9 (2,3,3-trimethyl-cyclopent-1-enyl)-acetic acid 
• 60067-97-2 3-isobutyloxy-6,6-dimethylcyclohex-2-en-1-one 
• 546-67-8 lead(IV) tetraacetate 
• 64-19-7 acetic acid 
• 563-80-4 3-methyl-butan-2-one 
• 78-94-4 methyl vinyl ketone 
• 163068-87-9 2-methyl-2-(3,3-dimethyl-4-oxopentyl)-1,3-dioxolane 
• 40441-35-8 3,4,4-trimethylcyclohexen-1-one 
• 130660-15-0 5-Methyl-5-(phenylthio)-2-hexanone 
• 163068-94-8 2-methyl-(3-methyl-3-phenylthiobutyl)-1,3-dioxolane 
• 1727-76-0 β-campholenonitrile 
• 91007-14-6 2,2-dimethyl-5-oxo-hexanoic acid ethyl ester 
• 562-46-9 4,4-dimethylcyclohexane-1,3-dione 
• 2513-93-1 (2,3,3-trimethyl-cyclopent-1-enyl)-acetic acid amide 

Downstream Products

• 28354-99-6 4,4-dimethyl-5-oxohexanoic acid 
• 681-57-2 2,2-dimethylglutaric acid 
• 40441-35-8 3,4,4-trimethylcyclohexen-1-one 
• 103393-39-1 3,4,4-trimethyl-cyclohex-2-enone semicarbazone 
• 75-25-2 Bromoform 
• 1149585-77-2 3,4,4-trimethylcyclohex-2-enamine 

Relevant articles and documents

A General Preparative Method for Carbonyl-Protected γ-Lithioketones via Reductive Lithiation. Synthetic Uses of the Bishomoenolate Equivalents

The mixed cuprates, generated by reductive lithiation of bis(phenylthio)acetals using lithium 4,4'-di-tert-butylbiphenylide (LDBB), followed by addition of cuprous bromide-dimethyl sulfide complex, undergo conjugate addition to enones in the presence of t

Alkyl Substituent Effects on the Photorearrangement of Cyclohex-2-en-1-ones to Lumiketones

The effect of alkyl substitution on the photorearrangement of cyclohex-2-en-1-ones to bicyclohexan-2-ones (lumiketones) was investigated.Contrary to earlier reports, both 2,4,4- and 3,4,4-trimethylcyclohex-2-en-1-one undergo this rearrangement upon