17576-75-9Relevant articles and documents
2,2,2-Trifluoroacetophenone as an organocatalyst for the oxidation of tertiary amines and azines to N-oxides
Limnios, Dimitris,Kokotos, Christoforos G.
, p. 559 - 563 (2014)
A cheap, mild and environmentally friendly oxidation of tertiary amines and azines to the corresponding Noxides is reported by using polyfluoroalkyl ketones as efficient organocatalysts. 2,2,2-Trifluoroacetophenone was identified as the optimum catalyst for the oxidation of aliphatic tertiary amines and azines. This oxidation is chemoselective and proceeds in high-to-quantitative yields utilizing 10 mol% of the catalyst and H2O2 as the oxidant.
Process for the preparation of amine oxides
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Page/Page column 7-8, (2008/06/13)
The present invention provides a process for the preparation of amine oxide by reacting a tertiary or a secondary amine with hydrogen peroxide as an oxidant in the presence of a recyclable heterogeneous catalyst comprising a layered double hydroxide exchanged with an anion in the presence of an additive selected from the group consisting of benzonitrile, propionitrile, isoburyronitrile, benzamide and isobutyramide.
Effect of geometry on the thermodynamic properties of micellar systems: trialkylamine oxides in water
Caron, Gaston,Gelinas, Nadia,Desnoyers, Jacques E.
, p. 1573 - 1580 (2007/10/02)
The apparent molar volumes, heat capacities, relative enthalpies, and isentropic compressibilities of symmetrical trialkylamine oxides and cyclohexyldimethylamine oxide were measured in water at 25 deg C.The data were in most cases analyzed with a mass-ac
